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Oxidation catalyst of iron oxide suppressing dioxin formation in polyethylene combustion
Authors:Tomoyuki Imai  Toshiki Matsui  Yasuhiko Fujii  Tasuku Nakai  Suminori Tanaka
Institution:(1) Toda Kogyo Corporation, 1-4 Meijishinkai, Otake, Hiroshima 739-0652, Japan Tel. +81-8275-9-0083; Fax +81-8275-7-3572 e-mail: Tomoyuki_Imai@todakogyo.co.jp, JP;(2) Okura Industrial Corporation, Marugame, Kagawa 763-8505, Japan, JP
Abstract:A new iron oxide catalyst, which has a superior oxidation activity in carbon monoxide and polyethylene (PE) combustion, was synthesized by an aqueous solution reaction. Catalytic oxidation of carbon monoxide over six kinds of hematite obtained from the goethite was done using a microcatalytic pulse reactor, and the composition of the hematite with the highest oxidation activity was determined. With the aim of suppressing dioxin formation on combustion, incineration tests of solid wastes in PE refuse bags with and without the goethite were carried out using a commercial semibatch-type incinerator with a combustion chamber of 6.2 m3. The result confirmed that the concentration of dioxins in the flue gas decreased considerably when the refuse was incinerated in PE bags manufactured with goethite. Received: July 24, 2000 / Accepted: October 18, 2000
Keywords:  Iron oxide  Carbon monoxide  Polyethylene combustion  Dioxins  Incinerator
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