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敌草快在水溶液中的光解动力学研究
引用本文:彭娟莹,杨仁斌.敌草快在水溶液中的光解动力学研究[J].环境科学与管理,2012,37(2):45-47.
作者姓名:彭娟莹  杨仁斌
作者单位:1. 湖南长沙环境保护职业技术学院,湖南长沙,410004
2. 湖南农业大学环境科学保护研究所,湖南长沙,410128
基金项目:农业部农药残留基金项目(RS155)
摘    要:常温常压条件下,用500 w高压汞灯和太阳光分别照射处理敌草快水溶液,考察光照和初始浓度对敌草快在水溶液中光降解的影响。研究表明,分别用500 w高压汞灯和太阳光照射下,敌草快的光解反应均符合一级动力学规律,降解半衰期分别为0.11 d和240.63 d;敌草快的初始浓度越大,其光解率越小,光解率与其初始浓度呈负相关。

关 键 词:除草剂  敌草快  光解动力学

Photolysis Kinetics of Diquat in Water
Peng Juanying,Yang Renbin.Photolysis Kinetics of Diquat in Water[J].Environmental Science and Management,2012,37(2):45-47.
Authors:Peng Juanying  Yang Renbin
Institution:1.Changsha Environmental Protection College,Changsha 410004,China; 2.Institute of Agro-Environmental Protection,Hunan Agricultural University,Changsha 410128,China)
Abstract:Diquat in water was irradiated at room temperature by a 500 w high pressure mercury lamps and sunlight,respectively.Influence of light and initial concentration of diquat on the photolysis was studied.The results showed that under the irradiation of 500 w high pressure mercury lamps and sunlight,the photolysis complied with first-order kinetics.The photolysis half-lives are 0.11 and 240.63d,respectively.The higher the initial diquat concentration was,the slower the photolysis rate became.The photolysis rate and the initial concentration are correlated negatively.
Keywords:herbicide  diquat  photolysis
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