沙土对可溶性油的吸附作用及其影响因素研究

在对滨海沙滩(胶州湾)沙土-水系统石油污染调查的基础上,选择代表性的沙滩进行取样,系统测定不同沙土对可溶性油的吸附动力学曲线和吸附等温线,并分析了含沙量、粒径、温度、pH和盐度对吸附作用的影响.结果表明,不同沙土的吸附动力学曲线和吸附等温线分别符合对数型和直线型理想吸附,沙土对可溶性油的吸附平衡时间约为6～10h;沙土对海水中可溶性油的吸附量随含沙量增大、温度升高、pH值的增大而减小,随盐度增加、沙土粒度变细其吸附量越大.另外,通过试验还发现,当水相中可溶性油低于一定浓度时,不但不产生吸附,反而使沙土中的残留油分解吸出来.

Adsorption of Aqueous oil on Sands and its Studies of Effective Factors

Representative sands were sampled on the basis of the investigation into the oil contamination of soil-water systems in the Jiaozhou-Bay. Kinetic curves and isotherms of aqueous oil adsorption on sands were measured and the influence of sand contents, sands under different size, temperature, pH and salt contents on the adsorption were studied. The research results show that dynamic curves of aqueous oil adsorption for sands are logarithmic and all the adsorption isotherms are straight, the equilibrium period of the adsorption is 6-10 hours, adsorption of aqueous oil on sands decreases with the increase of the sand contents,temperatures and pH, while increases with the increase of salinity and the more fine of the sands sizes. In addition, it was found that the sands release some oil when the aqueous oil concentrations are lower than certain values.