人工湿地设计及运行参数对挥发性烷基硫化物去除的影响

以中试规模的潜流人工湿地水处理试验场为对象,研究了床体长宽比、填料粒径、水位、水力负荷和温度(季节)等设计及运行参数对二甲基硫(DMS)及二甲基二硫(DMDS)等挥发性烷基硫化物去除的影响.通过1 a的运行及监测分析,结果表明,当湿地系统水力负荷为12~86 cm.d-1时,人工湿地系统对所研究的挥发性烷基硫化物具有很好地去除作用,对DMS及DMDS的去除率分别为86%及95%;方差分析表明,水力负荷和温度(季节)是影响所研究的污染物去除的2个主要因素;水力负荷对出口水中DMS的浓度有显著性影响(p0.01);温度(季节)对出口水中DMS及DMDS的浓度有显著性影响(p0.01);床体长宽比、填料粒径大小及水位对出口水中DMS及DMDS的浓度无显著性影响(p0.05).通过溶解氧和氧化还原电位的分析,发现本湿地系统内为强还原环境(Eh-300 mV),结合硫酸盐、硝酸盐、亚硝酸盐等电子受体及溶解有机物(如TOC及乙酸)浓度在湿地系统中的变化趋势,推测DMS及DMDS的去除主要是通过硫酸盐还原及产甲烷化作用进行的.

Effect of Design and Operation Parameters on Volatile Alkylsulfides Removal in Subsurface Constructed Wetlands

A pilot-scale subsurface constructed wetland wastewater treatment system was sampled for one year to study the effects of bed aspect ratio, substrate medium size, water depth, HLR (hydraulic loading rate) and temperature (season) on removal of volatile alkylsulfides such as DMS (dimethylsulfide) and DMDS (dimethyldisulfide). The yearly experimental results demonstrated that the system showed good performance for DMS and DMDS removal in wastewater under different HLR ranging from 12 cm·d^-1 to 86 cm·d^-1. The system could remove 86% of DMS, and 95% of DMDS, respectively. ANOVA statistical analysis shows that HLR and temperature (season) are major factors controlling the system performance for the target analytes. According to ANOVA test, the HLR caused significant differences (p<0.01) on the average DMS effluent concentrations, and temperature (season) caused significant differences (p<0.01) on the average DMS and DMDS effluent concentrations. However, bed aspect ratio, substrate medium size and water depth did not cause significant differences (p>0.05) on the average DMS and DMDS effluent concentrations. A survey of dissolved oxygen and ORP indicates that the constructed wetlands system showed strong reduced condition. On the basis of investigations of electron acceptors (such as SO^2-₄, NO^-₃ and NO^-₂) and dissolved organic pollutants (such as TOC and acetic acid) concentrations along with the length of constructed wetlands, it can be concluded that sulfate reduction and methanogenisis were estimated to be significant for DMS and DMDS removal in constructed wetland beds.