废旧阴极射线管(CRT)显示器玻壳进入土壤后铅的释放及转化

通过室内模拟试验，采用土壤连续提取法，探究废旧CRT显示器玻壳进入土壤环境后铅的释放及迁移转化过程.结果表明，土壤原始Pb总含量为28.4 mg/kg;按1∶20的玻壳/土壤质量比加入玻壳后土壤中Pb总含量为8 634.4 mg/kg，其中，溶解态和可交换态Pb(EXC-Pb)的含量为0.20～0.98 mg/kg，与碳酸盐结合的Pb(CARB-Pb)为20.1～103.6 mg/kg，与铁锰氧化物结合的Pb(RO-Pb)为26.7～54.3 mg/kg.上述3种形态Pb的总和为48.6～155.2 mg/kg.在EXC提取步骤中，直接从玻璃颗粒表面溶解的Pb含量为(0.038±0.025) mg/kg;而在CARB和RO提取步骤中，直接从玻璃颗粒表面溶解的Pb含量为(7.55±3.13) mg/kg.因此，CRT显示器玻壳进入土壤后，玻壳中的Pb释放并主要与土壤中CARB和RO矿物结合.加酸处理使土壤原位测定的pH值从8.0～8.3降低到7.1～7.5，但对土壤中Pb的形态没有产生显著影响.废旧CRT玻壳颗粒中的Pb向CARB、RO、EXC形态释放速率分别为21.1/t、　3.8/t、　0.15/t　mg·(kg·d)^-1 (t为处理时间，单位为d).当土壤pH或Eh值降低时，与CARB或RO结合的Pb可能转变为溶解与可交换态.因此，CRT玻壳颗粒进入土壤后Pb的释放会导致潜在的环境风险.

Release and Transform of Lead from the Glass of Cathode Ray Tube (CRT) Following Its Entrance in the Soil

The objective of this study was to investigate the release and transform Pb from the CRT glass following its entrance into the soil environment.A long-term incubation of soil mixed with CRT glass particles and sequential selective dissolution technology were used.Results indicated that the addition of CRT glass particle to the soil led to the increase in the total concentration of Pb in the soil from 28.4(mg/kg) to(8?634.4)(mg/kg).In details,the concentrations of Pb in the soluble and exchangeable form(EXC-...