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钙化合物的种类对脱氯特性的影响
引用本文:郭小汾,杨雪莲,李海滨,陈勇,李凡,谢克昌.钙化合物的种类对脱氯特性的影响[J].环境科学学报,2000,20(6):776-780.
作者姓名:郭小汾  杨雪莲  李海滨  陈勇  李凡  谢克昌
作者单位:1. 中国科学院广州能源研究所,广州,510070
2. 太原理工大学,太原,030024
基金项目:广东省科研项目,中国科学院特别支持项目,,KY957-03-03,,
摘    要:以PVC为HCl的释放源,采用热重法对不同气氛下各种钙化合物的脱氯特性进行了研究,探讨了各种钙化物的脱氯机理以及脱氯效率。结果表明和PVC作为氯化氢的释放源是可行的。3种钙化物中氢氧化钙的脱氯效果最好。氧化钙与氢氧化钙的脱氯机理基本相似。各种钙化物在不同气氛下的脱氯机理是不同的。燃烧状态下,在高温段钙化物脱氯产物氯化钙有分解迹象。

关 键 词:钙化物  聚氯乙烯  氯化氢  脱氯  垃圾焚烧  种类
收稿时间:1999/8/30 0:00:00
修稿时间:1999-8-30

The Characteristic of chlorine removal by calcium
GUO Xiaofen,YANG Xuelian,LI Haibin,CHEN Yong,L I Fan and XIE Kechang.The Characteristic of chlorine removal by calcium[J].Acta Scientiae Circumstantiae,2000,20(6):776-780.
Authors:GUO Xiaofen  YANG Xuelian  LI Haibin  CHEN Yong  L I Fan and XIE Kechang
Institution:Guangzhou Institute of Energy Conversion, ACS 510070,Guangzhou Institute of Energy Conversion, ACS 510070,Guangzhou Institute of Energy Conversion, ACS 510070,Guangzhou Institute of Energy Conversion, ACS 510070,Taiyuan University of Technology and Taiyuan University of Technology
Abstract:The mechanism and efficiency of chlorine removal by calcium in different atmospheres were investigated by means of thermogravimetry.The PVC was used as the chlorine emission source.The results indicated that PVC can be used as the chlorine emission surce.The efficiency of chlorine removal by Ca(OH)\-2 is the best in the three calcium compounds.The mechanism of chlorine removal by Ca(OH)\-2 is the same as by CaO.The chlorine removal mechanism in different atmospheres is individual.CaCl\-2 will be decomposed under high temperature.
Keywords:calcium  thermogravimetry  chlorine removal  
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