| 城市垃圾焚烧飞灰熔融DSC-DTA实验研究 |
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| 引用本文： | 李润东,池涌,李水清,王雷,严建华,岑可法.城市垃圾焚烧飞灰熔融DSC-DTA实验研究[J].环境科学,2002,23(4):113-117. |
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| 作者姓名： | 李润东 池涌 李水清 王雷 严建华 岑可法 |
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| 作者单位： | 浙江大学能源洁净利用教育部重点实验室,杭州,310027 |
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| 基金项目： | 国家自然科学基金重点项目(59836210);国家自然科学基金项目(50076037);浙江省自然科学基金青年科技人才培养专项基金项目(RC99041) |
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| 摘 要： | 利用高温DSC-DTA热分析仪对国内外2种城市垃圾焚烧飞灰在惰性气氛(N2)和氧化气氛(O2)下的熔融特性进行了研究.在20℃～1450℃的温度范围内采用3种温升速率进行实验.飞灰熔融过程包含多晶转变和熔融相变2种反应,多晶转变发生在480℃～670℃范围内,吸热量20kJ/kg;熔融约发生在1136℃～1231℃,在1174℃达到峰值,熔融相变潜热约700 KJ/kg,整个过程总吸热量约1800 kJ/kg.研究了CaO添加剂对飞灰熔融的影响.最后提出飞灰熔融吸热量的预测模型,模型
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| 关 键 词： | 城市垃圾 飞灰 熔融 DSC-DTA |
| 文章编号： | 0250-3301(2002)04-05-0113 |
| 收稿时间： | 2001/8/17 0:00:00 |
| 修稿时间： | 2001年8月17日 |
MSW Incineration Fly Ash Melting by DSC-DTA |
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| Li Rundong,Chi Yong,Li Shuiqing,Wang Lei,Yan Jianhu and Cen Kefa.MSW Incineration Fly Ash Melting by DSC-DTA[J].Chinese Journal of Environmental Science,2002,23(4):113-117. |
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| Authors: | Li Rundong Chi Yong Li Shuiqing Wang Lei Yan Jianhu and Cen Kefa |
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| Institution: | National Key Lab of MOE Clean Energy and Environment Engineering, Zhejiang University, Hangzhou 310027, China. |
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| Abstract: | Melting characteristics of two kinds of municipal solid waste incineration(MSWI) fly ash were studied in this paper by high temperature differential scanning calorimetry and differential temperature analysis. MSWI fly ash was considered as hazardous waste because it contains heavy metals and dioxins. The experiments were performed in either N2 or O2 atmosphere in temperature range of 20 degrees C-1450 degrees C at various heating rates. Two different MSW incineration fly ashes used in the experiments were collected from our country and France respectively. The process of fly ash melting exhibits two reactions occurring at temperature ranges of about 480 degrees C-670 degrees C and 1136 degrees C-1231 degrees C, respectively. The latent heat of polymorphic transformation and fusion were approximately 20 kJ/kg and 700 kJ/kg, while the total heat required for melting process was about 1800 kJ/kg. The paper also studied effect of CaO to melting. A heat flux thermodynamic model for fly ash melting was put forward and it agrees well with experimental data. |
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| Keywords: | municipal solid waste fly ash melting DSC DTA |
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