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Fungal degradation of an acetolactate synthase (ALS) inhibitor pyrazosulfuron-ethyl in soil
Authors:Shobha Sondhia  Uzma Waseem  RK Varma
Institution:1. Department of Chemistry, Directorate of Weed Science Research, Adhartal, Jabalpur, MP, India;2. Department of Microbiology, Mata Gujri Girls College, Jabalpur, MP, India;3. Department of Plant Pathology, College of Agriculture, Jawaharlal Agricultural University, Jabalpur, MP, India
Abstract:Owing to reported phytotoxicity of some sulfonylurea class of herbicides in number of sensitive crops and higher persistence in soil, present study was conducted to isolate and identify pyrazosulfuron-ethyl degrading fungi from soil of rice field. Penicillium chrysogenum and Aspergillus niger, were isolated and identified from rhizospere soil of rice field, as potent pyrazosulfuron-ethyl degrading fungi. Degradation of pyrazosulfuron-ethyl by P. chrysogenum and A. niger, yielded transformation products/metabolites which were identified and characterized by LC/MS/MS. The rate of dissipation of pyrazosulfuron-ethyl was found higher in soil of rice field and soil inoculated with P. chrysogenum. This showed important route of degradation of pyrazosulfuron-ethyl by microbes apart from chemical degradation.
Keywords:Degradation  Pyrazosulfuron-ethyl  Herbicide  Penicillium chrysogenum  Aspergillus niger  Dissipation
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