碳氮比对UniFed SBR工艺性能的影响

采用UniFed SBR工艺试验装置处理实际生活污水,考察了7组不同的进水碳氮比(2.75、4.28、5.7、6.5、6.97、8.08、11.19)对总氮、磷和COD去除以及污泥沉降性能的影响.结果表明,当C/N低于5.7时, TN去除率随C/N的升高而快速大幅度提高,从2.75时的43.6%升至5.7时的80.84%,之后继续提高C/N,由于不能进一步提高进水/排水阶段的脱氮率,只能提高曝气阶段由于同步硝化反硝化产生的脱氮率,所以TN去除率的提高变得缓慢.随着进水C/N的增加,聚磷菌可从进水中获得更多的有机碳源,进行PHB的合成和PO3-4的释放,同时避免了NO-x;对释磷产生的抑制作用,因而磷的去除率随C/N的增加而提高,且C/N越高, PAOs的释磷量和吸磷量越多,好氧吸磷速率越快,除磷效果越好.进水C/N的变化对COD的去除没有显著影响,平均去除率为93.15%.当C/N大于6.97、有机负荷高于0.38kg/(kg·d)时,污泥容积指数随C/N的增加而大幅度提高,产生由于低溶解氧和高负荷带来的非丝状菌污泥膨胀.

Effects of Influent C/N Ratio on Performance of UniFed SBR Process

The effects of 7 groups of different influent C/N ratio (2.75, 4.28, 5.7, 6.5, 6.97, 8.08, 11.19) on the removal efficiencies of total nitrogen, phosphorus and COD as well as the sludge settling performance were investigated in a UniFed SBR lab-scale apparatus treating actual domestic wastewater. The results showed that when the C/N ratio was lower than 5.7, TN removal efficiency increased sharply as C/N ratio increased, from 43.6% of 2.75 to 80.84% of 5.7. Afterwards, TN removal efficiency increased very slowly as C/N ratio increased, because only TN removal efficiency caused by SND during aeration period could be enhanced. P removal efficiency increased as C/N ratio increased, because PAOs could get more organic carbon source from the influent to produce PHB and release PO4(3-), avoiding the adverse influence of NO(x)- on PO4(3-) release. The higher the C/N ratio, the more the quantities of P release and uptake, the quicker P uptake rate, the better P removal performance was. Regardless of the C/N ratio, excellent COD (average 93.15%) removal efficiencies were maintained throughout the experiment. When Influent C/N ratio was bigger than 6.97 and organic load exceeded 0.38 kg/(kg x d), SVI rose quickly as C/N ratio increased. Non-silk bacteria sludge bulge appeared because of low DO and high organic load.