土壤固相吸附砷的研究进展

砷是一种常见的有毒元素，土壤砷污染与修复问题已引起世界范围的广泛关注。土壤原位修复是消除土壤砷污染的有效方法，其中砷在土壤固相上的吸附也是近年来的研究热点。土壤固相广泛存在于土壤中，并具有表面积大和表面电荷等理化性质，它可通过与砷酸根阴离子发生表面配位反应，形成内外层配位体等方式来固定土壤中的砷，以降低金属离子的迁移能力和有效性，是一种有效的原位减轻砷污染的方法。文中简单介绍了砷污染的现状、危害和赋存状态，重点介绍了铁铝锰的氧化物和氢氧化物、粘土矿物、有机质等土壤固相对砷的吸附机理及其影响因素，旨在更好地掌握砷的吸附行为。

Advances in Study on Arsenic Adsoption on Soil Solid Phases

The pollution and remediation of arsenic is of increasing concern due to its high toxicity and widespread occurrence in the environment.Situ remediation of As-polluted soils is one of the most effective options,among which the adsorption of arsenic on soil solid phases attracts more attention.Soil solid phases are widely distributed in soils with a large surface area and charge.Arsenic can form inner-sphere or outer-sphere complexes on the surfaces of the solid phases through ligand exchange to reduce its m...