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氧化还原电位的研究及应用
引用本文:向交,徐丽萍,李和平,李娟,唐镜淞.氧化还原电位的研究及应用[J].地球与环境,2014,42(3):430-436.
作者姓名:向交  徐丽萍  李和平  李娟  唐镜淞
作者单位:中国科学院地球化学研究所地球内部物质高温高压实验室;中国科学院大学;
基金项目:国家“863”计划资助项目(2010AA09Z207);中国科学院重大科研装备研制项目(YZ200720);国家自然科学基金资助项目(41006061);中国科学院地球化学研究所“135”项目
摘    要:氧化还原电位(Eh)是一个描述介质氧化还原性质相对程度的化学参数,根据Eh值可以直观的比较介质氧化还原性的强弱。氧化性强,Eh值较高;还原性强,Eh值较低。氧化还原电位的测定广泛应用于水处理、土壤环境监测、金属腐蚀、湿法冶金和资源勘探等领域。本文综述了氧化还原电位在常温常压环境和高温高压环境中众多领域的应用现状,并展望了高温高压水热环境中氧化还原电位原位监测的研究。

关 键 词:氧化还原电位  湿法冶金  金属腐蚀  高温高压
收稿时间:2013/9/23 0:00:00
修稿时间:2013/12/15 0:00:00

Research on and Application of Oxidation-reduction Potential
XIANG Jiao,XU Li-ping,LI He-ping,LI Juan,TANG Jing-song.Research on and Application of Oxidation-reduction Potential[J].Earth and Environment,2014,42(3):430-436.
Authors:XIANG Jiao  XU Li-ping  LI He-ping  LI Juan  TANG Jing-song
Institution:1. Laboratory for High Temperature & High Pressure Study of the Earth''s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China;2. University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:Oxidation-reduction potential (Eh) is a chemical parameter for determining the oxidizing or reducing properties of media. Eh is reported with a numeric value, which represents oxidization when it increases and reduction when it decreases, relatively. The measurements of Eh can be applied to water treatment, soil environment monitoring, metal corrosion, hydrometallurgy, resource exploration and some other fields. In this paper, various applications of oxidation-reduction potential are summarized, including its measurements at normal temperature and pressure conditions, as well as its measurements at high temperature and high pressure conditions. In addition, the prospects of in-situ Eh measurement at high temperature and high pressure conditions are also described.
Keywords:oxidation-reduction potential  hydrometallurgy  metal corrosion  high temperature and high pressure
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