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改性膨润土颗粒对微污染水中有机物和氨氮的吸附
引用本文:陈仕稳, 聂锦旭, 谢伟楠, 胡立华, 关文贤. 改性膨润土颗粒对微污染水中有机物和氨氮的吸附[J]. 环境工程学报, 2015, 9(6): 2739-2744. doi: 10.12030/j.cjee.20150632
作者姓名:陈仕稳  聂锦旭  谢伟楠  胡立华  关文贤
作者单位:1.广东工业大学土木与交通工程学院, 广州 510006
基金项目:国家自然科学基金资助项目(51308131) 广东省教育部产学研项目(2012B090400030)
摘    要:采用粘结剂聚乙烯醇(PVA)、造孔剂碳酸氢钠(NaHCO3)和微波强化Al改性膨润土(以下简称M-Al-Bt)制备改性膨润土颗粒(以下简称MBG),研究MBG对微污染水中有机物和氨氮(NH4-N)的吸附效果,考察了不同投加量、反应时间、pH值对腐殖酸(HA)和NH4-N的去除效果影响.结果表明,投加量3 g/L,反应时间20 min,pH=7时,MBG对微污染水中20 mg/L HA和5mg/L NH4-N的去除率分别可达98%和20%以上.HA和NH4-N共存时,存在竞争吸附,HA影响了MBG对NH4-N的去除.

关 键 词:改性膨润土颗粒   微污染水   有机物   氨氮
收稿时间:2015-03-20

Adsorption of organic matters and ammonia-nitrogen in micro-polluted water by modified bentonite granules
Chen Shiwen, Nie Jinxu, Xie Weinan, Hu Lihua, Guan Wenxian. Adsorption of organic matters and ammonia-nitrogen in micro-polluted water by modified bentonite granules[J]. Chinese Journal of Environmental Engineering, 2015, 9(6): 2739-2744. doi: 10.12030/j.cjee.20150632
Authors:Chen Shiwen  Nie Jinxu  Xie Weinan  Hu Lihua  Guan Wenxian
Affiliation:1.School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China
Abstract:Modified bentonite granules(MBG) were prepared by using polyvinyl alcohol(PVA) as binder, sodium bicarbonate(NaHCO3) as pore-former and microwave enhanced Al-bentonite(M-Al-Bt) as raw material. The adsorption effect of MBG on organic matters and ammonia-nitrogen(NH4-N) in micro-polluted water was studied. Effects of MBG dosage, adsorption time, pH value on humic acid(HA) and NH4-N were investigated. The results showed that under the following conditions, MBG dosage of 3 g/L, adsorption time of 20 min, pH value of 7, the removal rate of HA and NH4-N were up to 98% and 20%, respectively at HA concentration of 20 mg/L and NH4-N concentration of 5 mg/L in micro-polluted water. There was a competitive adsorption between HA and NH4-N, the removal efficiency of MBG on NH4-N was affected by HA.
Keywords:modified bentonite granules  micro-polluted water  organic matters  ammonia-nitrogen
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