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几种试剂对硝酸根光催化脱色甲基橙的影响
引用本文:李建章,冯发美,蒋维东,曾俊,黄生田.几种试剂对硝酸根光催化脱色甲基橙的影响[J].环境工程学报,2009,3(5):854-856.
作者姓名:李建章  冯发美  蒋维东  曾俊  黄生田
作者单位:四川理工学院化学系催化研究所,自贡,643000
基金项目:四川省教育厅重大培育项目(07ZZ020)
摘    要:以NO-3为光催化剂,在紫外灯照射下,对甲基橙溶液进行光催化脱色。结果表明,叔丁醇、甲醇和乙醇对催化脱色反应有抑制作用; KBr和Na2SO4对脱色反应均有促进作用;而且KBr的加入量存在最佳值; Na2SO4的促进作用随Na2SO4的量的增加逐渐增强。Na2CO3的存在对甲基橙的脱色反应没有影响。K2S3O8和NO-3之间存在较强的协同作用;KIO3和NO-3之间存在相加作用;KBrO3和NO-3之间存在拮抗作用。

关 键 词:光催化脱色  甲基橙染料废水试剂

Influence of several reagents on photocatalytic decolorization of methyl orange with NO-3
Li Jianzhang,Feng Famei,Jiang Weidong,Zeng Jun and Huang Shengtian.Influence of several reagents on photocatalytic decolorization of methyl orange with NO-3[J].Techniques and Equipment for Environmental Pollution Control,2009,3(5):854-856.
Authors:Li Jianzhang  Feng Famei  Jiang Weidong  Zeng Jun and Huang Shengtian
Institution:Institute of Catalysis, Departmemt of Chemistry, Sichuan University of Science and Engineering, Zigong 643000,Institute of Catalysis, Departmemt of Chemistry, Sichuan University of Science and Engineering, Zigong 643000,Institute of Catalysis, Departmemt of Chemistry, Sichuan University of Science and Engineering, Zigong 643000,Institute of Catalysis, Departmemt of Chemistry, Sichuan University of Science and Engineering, Zigong 643000 and Institute of Catalysis, Departmemt of Chemistry, Sichuan University of Science and Engineering, Zigong 643000
Abstract:The NO-3 was used to decolorize the methyl orange (MO) solution with ultraviolet radiation. Influence of several reagents on photocatalytic decolorization of methyl orange with NO-3 was investigated. The results indicate that t-BuOH, ethanol and methanol can press the decolorization reaction, KBr and Na2SO4 can promote the decolorization reaction, there is an optimal amount of KBr in this case and the effects of Na2SO4 increase with the concentrations, while Na2CO3 has no obvious influence on the decolorization reaction. The synergy between K2S2O8 and NO-3 is very strong.There is no synergy between KIO3 and NO-3, while there is inhibitation between KBrO3 and NO-3.
Keywords:NO3-
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