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环境中金属有机化合物形态分析方法近期进展
引用本文:黄国兰,黄玉明.环境中金属有机化合物形态分析方法近期进展[J].环境工程学报,1993(3).
作者姓名:黄国兰  黄玉明
作者单位:南开大学环境科学系,南开大学环境科学系 天津,300071,天津,300071
摘    要:本文综合了环境中金属有机化合物形态分析方法的近期进展。在分离方面,高效液相色谱法(HPLC)的应用逐渐增加;等离子体激发的原子发射光谱作为检测器其应用也不断增长;HPLC与炉式原子吸收在接口上的困难已经解决;新的衍生技术已用于非挥发性物质的衍生以便于气相色谱分离;序列分析系统如GC/HPLC—AAS、GC/HPLC—AED、GC/HPLC—MS等的应用逐渐增多,所有这些联用系统都是相当灵敏的,而且很特效。

关 键 词:分析方法  金属有机化合物  综述

RECENT DEVELOPMENTS IN THE TECHNIQUES OF SPECIATION OF ORGANOMETALLIC COMPOUNDS IN THE ENVIRONMENT
Huang Guolan Huang Yuming.RECENT DEVELOPMENTS IN THE TECHNIQUES OF SPECIATION OF ORGANOMETALLIC COMPOUNDS IN THE ENVIRONMENT[J].Techniques and Equipment for Environmental Pollution Control,1993(3).
Authors:Huang Guolan Huang Yuming
Abstract:This paper presents a review of recent developments in speciation of organometallic compounds in the environment. On the separation purpose, high performance liquid chromatography is increadingly used. There is an increasing application of plasma-excited atomic emission spec-trometry as detector. The difficulty in interfacing of HPLC to furnace AAS have been overcome. New techniques are used in the derivatization of non-volatile species for gas chromatography. There is an increasing trend in the use of tandem analytical system such as GC/HPLC-AAS, GC/HPLC-AED, GC/HPLC-MS. All these combination systems are sophisticated, extremely sensitive and specific.
Keywords:analytical method  comment  organometallic compound
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