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KIO_4光催化脱色甲基橙的研究
引用本文:廉安,钟俊波,李建章,曾俊,马迪,孟庆明.KIO_4光催化脱色甲基橙的研究[J].环境科学与技术,2008,31(10).
作者姓名:廉安  钟俊波  李建章  曾俊  马迪  孟庆明
作者单位:四川理工学院,四川,自贡,643000
基金项目:四川省教育厅重大培育项目
摘    要:以KIO4为催化剂,对甲基橙进行了光催化脱色研究。结果表明甲基橙的脱色率随着催化剂量的增加而增加,但是没有一个最佳的量。当甲基橙浓度低于16mg/L时,反应为拟一级动力学反应,但是反应不符合Langmuir-Hinshewood动力学模型。脱色率在酸性条件下比碱性条件较高。高碘酸钾光催化脱色甲基橙的机理不完全是羟基自由基进攻。

关 键 词:KIO4  光催化脱色  甲基橙  废水处理

Photocatalytic Decolorization of Methyl Orange with KIO4
LIAN An,ZHONG Jun-bo,LI Jian-zhang,ZENG Jun,MA Di,MENG Qing-ming.Photocatalytic Decolorization of Methyl Orange with KIO4[J].Environmental Science and Technology,2008,31(10).
Authors:LIAN An  ZHONG Jun-bo  LI Jian-zhang  ZENG Jun  MA Di  MENG Qing-ming
Abstract:Photocatalytic decolorization of methyl orange(MO) with KIO4 was investigated.Results showed that decolorization of MO increased as the dosage of catalyst increased and without an optimal amount of catalyst.The decolorization reaction was a pseudo first-order reaction when concentration of MO was below 16mg/L,but it cannot be described by Langmuir-Hinshewood kinetic model.Decolorization efficiency in acid was better than that in base.Results indicated that mechanism was different from sole hydroxyl radical attacks in MO degradation with H2O2 by UV irradiation.
Keywords:KIO4
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