| 水中微量甲基膦酸类化合物的树脂富集与GC／MS分析 |
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| 引用本文： | 周黎明,顾惠芬.水中微量甲基膦酸类化合物的树脂富集与GC／MS分析[J].环境化学,1998,17(2):186-190. |
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| 作者姓名： | 周黎明 顾惠芬 |
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| 作者单位： | 防化指挥工程学院第八教研室，防化指挥工程学院第八教研室，防化指挥工程学院第八教研室，防化指挥工程学院第八教研室 北京，102205，北京，102205，北京，102205，北京，102205 |
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| 摘 要： | 本文使用三种阴离子交换树脂（即大孔弱碱型Ｄ－３０１－Ｒ，强碱型Ｄ－２９６，２０１Ｘ７）柱对水中微量甲基膦酸类化合物的富集方法进行了研究。含磷毒剂降解产物的水样用气相色谱／质谱法进行定性定量分析。结果表明，Ｄ－３０１－Ｒ阴离子交换树脂柱对甲基膦酸的富集回收率高于６０％。
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| 关 键 词： | 甲基膦酸 树脂富集 水样 水质监测 GC MS |
ANALYSIS OF METHYLPHOSPHONIC ACIDS IN WATER BY ANION EXCHANGE RESIN ENRICHMENT AND GAS CHROMATOGRAPHY-MASS SPECTROMETRY |
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| Zhou Liming,Gu Huifen,Qu Ganglian,Zhong Yuzheng.ANALYSIS OF METHYLPHOSPHONIC ACIDS IN WATER BY ANION EXCHANGE RESIN ENRICHMENT AND GAS CHROMATOGRAPHY-MASS SPECTROMETRY[J].Environmental Chemistry,1998,17(2):186-190. |
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| Authors: | Zhou Liming Gu Huifen Qu Ganglian Zhong Yuzheng |
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| Abstract: | Three anion ion-exchange resins(i. e. D-301-R weak basic,D-296 and 201X7 strong basic respectively) were used for the enrichment of methylphosphonic acids in water. Their degradation products were retained on the resins and eluted with saturated anhydrous HCl/methanol solution, then the eluted solution was methylated with dia-zomethane. Finally, the methylating compounds were identified and quantified by gas chromatography-mass spectrometry (EI mode). It was found that the recovery of methylphosphonic acid in water was over 60% when the macroporous weak alkali anion exchange resin D-301-R was applied in the study. . |
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| Keywords: | methylphosphonic acids anion exchange resin enrichement water sample derivatization gas chromatography-mass spectrometry |
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