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用流动电流技术研究聚硅氯化铝混凝剂的电动特性
引用本文:高宝玉,王占生,汤鸿霄.用流动电流技术研究聚硅氯化铝混凝剂的电动特性[J].中国环境科学,1999,19(6):0-0.
作者姓名:高宝玉  王占生  汤鸿霄
作者单位:1.山东大学环境工程系 山东济南250100;2.清华大学环境科学与工程系 北京100084;3.中国科学院生态环境中心国家重点水化学实验室 北京100085
基金项目:国家自然科学基金!59878036,“九五’国家科技攻关!96-909-03-02
摘    要:采用流动电流(SC)技术,研究比较了聚硅氯化铝(PASC)与聚合氯化铝(PAC)的电动特性.研究结果表明,在PASC中,由于带负电荷的聚硅酸与铝水解聚合产物间的相互作用,使得PASC的电中和能力较PAC有所下降,其下降程度与PASC的碱化度(B)和Al/Si摩尔比密切相关,B值和Al/Si摩尔比越小,则PASC的电中和能力就越弱.制备工艺对PASC的电中和能力略有影响.

关 键 词:聚硅氯化铝(PASC)混凝剂  流动电流(SC)  电动特性  碱化度(B)  Al/Si摩尔比  
收稿时间:1900-01-01;

Electrokinetic characteristic of flocculant polyaluminum silicate chloride(PASC) by streaming current measurement
GAO Bao-yu,WANG Zhan-sheng,TANG Hong-xiao.Electrokinetic characteristic of flocculant polyaluminum silicate chloride(PASC) by streaming current measurement[J].China Environmental Science,1999,19(6):0-0.
Authors:GAO Bao-yu  WANG Zhan-sheng  TANG Hong-xiao
Institution:GAO Bao-yu; (Department of Environmental Engineering, Shandong University, Jinan 250100,China); WANG Zhan-sheng; (Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China); TANG Hong-xiao; (State Key Laboratory of Environmental Aquatic Chemistry,Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China). China Environmental Sciences. 1999,19(6)
Abstract:The electrokinetic characteristics of polyaluminum silicate chloride flocculant (PASC) and polyaluminumchloride (PAC) were studied and compared by streaming current (SC) technique. The outcome results shows that the interaction between polysilicic acid with negative charge and hydrolyzed aluminum species results in the decrease of thecharge-neutralizing ability of PASC as in comparison with PAC, the charge-neutralizing ability of PASC has close relationwith the basicity (B) and Al/Si molar ratio in PASC. The less the B value and Al/Si molar ratio, the lower the chargeneutralizing ability of PASC. The preparation technique for PASC affects the charge-neutralization of PASC to a littleextent.
Keywords:polyaluminum silicate chloride flocculant (PASC)  streaming current (SC)  electrokinetic characteristic:basicity (B)  Al/Si molar ratio
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