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Efficient reduction and adsorption of Cr(Ⅵ) using FeCl3-modified biochar:Synergistic roles of persistent free radicals and Fe(Ⅱ)
作者姓名:Shujie Hu  Chengshuai Liu  Hongling Bu  Manjia Chen  Ying-heng Fei
作者单位:1. National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China,Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and Management,Institute of Eco-environmental and Soil Sciences,Guangdong Academy of Sciences;2. College of Resources and Environment,Chongqing School,University of Chinese Academy of Sciences;3. State Key Laboratory of Environmental Geochemistry,Institute of Geochemistry,Chinese Academy of Science;4. School of Environmental Science and Engineering,Guangdong University of Technology;5. School of Environment Science and Engineering,Guangzhou University
基金项目:supported by the National Key Research and Development Program of China (No. 2020YFC1808500);;the National Natural Science Foundation of China (Nos. 42107046 and 41907119);;the Postdoctoral Science Foundation of China (No. 2020M682634);;the Guangdong Basic and Applied Basic Research Foundation (No. 2021A1515011540);
摘    要:Transition metal iron and persistent free radicals(PFRs) both affect the redox properties of biochar, but the electron transfer relationship between them and the coupling reduction mechanism of Cr(Ⅵ) requires further investigation. To untangle the interplay between iron and PFRs in biochar and the infuences on redox properties, FeCl3-modified rice husk biochar(FBCs) was prepared and its reduction mechanism for Cr(Ⅵ) without light was evaluated. The FBCs had higher surface positive cha...

收稿时间:2022-12-14
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