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| 气相色谱法测定二硫化碳和甲硫醚 | |
| 引用本文： | 吴诗剑,李冰清,夏凡,张红卫. 气相色谱法测定二硫化碳和甲硫醚[J]. 环境科学与技术, 2004, 27(Z1): 35-36 |
| 作者姓名： | 吴诗剑 李冰清 夏凡 张红卫 |
| 作者单位： | 上海市环境监测中心,上海,200030 |
| 摘 要： | 利用气相色谱(配火焰光度检测器,采用3mxφ2mm玻璃填充柱分离)对CS2和甲硫醚(DMS)两种含硫化合物进行了分离检测。该方法具有较高的灵敏度和良好的线性关系。结果表明:该分析对含硫气体的最小检测浓度在mg/m3级,在柱温为70℃,检测器温度为180℃,气化室温度为150℃,氮气流速为50mL/min时,CS2的回收率为98.66%,变异系数为2.12%;甲硫醚的回收率为98.66%,变异系数为1.56%。 |
| 关 键 词： | CS2 甲硫醚 恶臭 气相色谱 |
| 文章编号： | 1003-6504(2004)增-0035-03 |
| 修稿时间： | 2004-02-06 |
Measurement of Carbon Disulfide and Dimethyl Sulfide with Gas Chromatography |
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| WU Shi-jian,LI Bing-qing,XIA Fan,ZHANG Hong-wei. Measurement of Carbon Disulfide and Dimethyl Sulfide with Gas Chromatography[J]. Environmental Science and Technology, 2004, 27(Z1): 35-36 | |
| Authors: | WU Shi-jian LI Bing-qing XIA Fan ZHANG Hong-wei |
| Abstract: | Gas chromatography was used to analyze two volatile sulphur compounds gases as CS_2 and DMS, with higher sensitivity and linearity. Results showed that the minimum detecting concentration of sulphur compounds was up to mg/m~3 level. With the column temperature in 70℃, injector temperature in 180℃, detector temperature in 150℃, and N_2 flow rate at 50mL/min, the recovery of carbon disulfide was 98.66%, and relative standing deviation was 2.12%, while the recovery of dimethyl sulphide was 98.66%, and relative standing deviation was 1.56%. |
| Keywords: | carbon disulfide dimethyl sulfide odorous gas gas chromatography |
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