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Efficient and recyclable palladium enriched magnetic nanocatalyst for reduction of toxic environmental pollutants
Authors:Manjunatha Kempasiddaiah  Vishal Kandathil  Ramesh B Dateer  Mahiuddin Baidy  Shivaputra A Patil  Siddappa A Patil
Institution:Centre for Nano and Material Sciences, Jain University, Jain Global Campus, Kanakapura, Ramanagaram,Bangalore 562112, India;Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, Tamil Nadu, India;Pharmaceutical Sciences Department, College of Pharmacy, Rosalind Franklin University of Medicine and Science,North Chicago,IL 60064, USA
Abstract:In this paper, highly stable, powerful, and recyclable magnetic nanoparticles tethered N-heterocyclic carbene-palladium(II) ((CH3)3email protected]3O4) as magnetic nanocatalyst was successfully synthesized from a simplistic multistep synthesis under aerobic conditions through easily available low-cost chemicals. Newly synthesized (CH3)3email protected]3O4 magnetic nanocatalyst was characterized from various analytical tools and catalytic potential of the (CH3)3email protected]3O4 magnetic nanocatalyst was studied for the catalytic reduction of toxic 4-nitrophenol (4-NP), hexavalent chromium (Cr(VI)), Methylene Blue (MB) and Methyl Orange (MO) at room temperature in aqueous media. UV-Visible spectroscopy was employed to monitor the reduction reactions. New (CH3)3email protected]3O4 magnetic nanocatalyst exhibited excellent catalytic activity for the reduction of toxic environmental pollutants. Moreover, (CH3)3email protected]3O4 magnetic nanocatalyst could be easily and rapidly separated from the reaction mixture with the help of an external magnet and recycled minimum five times in reduction of 4-NP, MB, MO and four times in Cr(VI) without significant loss of catalytic potential and remains stable even after reuse.
Keywords:Corresponding author    Magnetic nanocatalyst  Wastewater treatment  Chemical kinetics  Catalyst recyclability
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