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Degradation of the herbicide imazapyr by Fenton reactions
Authors:Ghizlaine?Kaichouh  Nihal?Oturan  Email author" target="_blank">Mehmet?A?OturanEmail author  Kacem?El?Kacemi  Abderrahim?El?Hourch
Institution:(1) Laboratoire des Géomatériaux, CNRS FRE 2455, Université de Marne-la-Vallée, Champs-sur-Marne, France;(2) Laboratoire drsquoElectrochimie et de Chimie Analytique, Faculté des Sciences, Université Mohammed V-Agdal, Rabat, Morocco
Abstract:The degradation of the herbicide imazapyr has been carried out by three advanced oxidation processes involving iron ions as catalysts: Fentonrsquos reagent, photo-Fenton and electro-Fenton. We show that all processes are rapid and efficient. The kinetic rate constant was found to be k=5.4×109 M–1 s–1. The mineralization of imazapyr is almost complete using the photo-Fenton and electro-Fenton processes.
Keywords:Imazapyr  Hydroxyl radicals  Fentonrsquos reagent" target="_blank">gif" alt="rsquo" align="BASELINE" BORDER="0">s reagent  Photo-Fenton  Electro-Fenton  Mineralization  Chemical oxygen demand
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