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氯氟烃替代物大气化学研究
引用本文:陈忠明,李金龙,唐孝炎.氯氟烃替代物大气化学研究[J].环境科学,1997,18(4):85-89.
作者姓名:陈忠明  李金龙  唐孝炎
作者单位:北京大学技术物理系,北京大学环境科学中心
摘    要:大气平流层臭氧(大气臭氧层)由于能够吸收太阳辐射中的高能量紫外线,对人类和生物起着非常重要的保护作用,氯氟烃类化合物(CFCs)已被认为是造成大气平流层臭氧耗损的主要原因,淘汰CFCs和使用替代物日趋紧迫,目前,最有应用前景的替代物是含氢氧氟烃类化合物(HCFCs)和氢氟烃类化合物(HFCs),其中有些已投入工业使用,本文总结 了HCFCs和HFCs在气中的光化学降解机制及其产物,以及产物对环境的

关 键 词:CFCs  大气化学  HCFCs  HFCs  大气单流层  臭氧
收稿时间:1/5/1997 12:00:00 AM

The Study of Atmospheric Chemistry of CFC Substitutes
Chen Zhongming,Li Jinlong and Tang Xiaoyan.The Study of Atmospheric Chemistry of CFC Substitutes[J].Chinese Journal of Environmental Science,1997,18(4):85-89.
Authors:Chen Zhongming  Li Jinlong and Tang Xiaoyan
Institution:Dept. of Technical Physics, Peking University, Beijing 100871;Dept. of Technical Physics, Peking University, Beijing 100871;Center of Environmental Sciences, Peking University, Beijing
Abstract:Chlorofluorocarbons(CFCs)have been regarded as the main course for the depletion of stratospheric ozone. To protect the strato-spheric ozone layer, the phaseout of the CFCs and the use of CFC substitutes are being implemented. At present, hydrochlor of luorocar bons(HCFCs)and hydrofluoro-carbons(HFCs)are the most hopeful substitutes, and some of them have been used in the industry. This paper reviews mechanisms and products of photo-chemical deg radation of HCFCs and HFCs in the atmosphere, and the environmental effect of products.
Keywords:CFC substitutes  atmospheric chemistry  reaction mechanism  products
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