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Secular trends of atmospheric methane (CH4)
Authors:MAK Khalil  RA Rasmussen
Institution:Department of Environmental Science, Oregon Graduate Center Beaverton, Oregon 97006, U.S.A.
Abstract:Due partly to human activities the present yearly emissions of CH4 exceed the atmospheric sinks, thus leading to a 1.2–1.9% per year atmospheric increase in the concentration of CH4. New evidence based on studies of polar ice cores suggests that several hundred years ago the concentrations of CH4 were perhaps only half of current values. These diverse findings are tied together in a single unified logistic model of atmospheric concentrations past, present and future. Using realistic growth rates of the sources of CH4 caused by human activities, the model explains the concentrations and current growth rates. It also predicts that a doubling of CH4 relative to present levels is possible given the long (9-year) atmospheric lifetime. Such increases of CH4 concentrations may have already perturbed our global environment and may continue to do so in the future. The environmental effects include increased surface temperature of the earth, additional O3 and CO in the clean non-urban atmosphere, depletions of tropospheric OH radicals, but perhaps also protection of the stratospheric ozone layer from destruction by man-made fluorocarbons.
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