Development of Anticorrosive Poly(Ether-Urethane) Amide Coatings from Linseed Oil: A Sustainable Resource |
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Authors: | Manawwer Alam S M Ashraf Alok R Ray Sharif Ahmad |
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Institution: | (1) Centre for Biomedical Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India;(2) Biomedical Engineering Unit, All India Institute of Medical Science, New Delhi, 110029, India;(3) Materials Research Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi, 110025, India |
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Abstract: | Polyetheramide(PEtA) resin was synthesized by the condensation polymerization of N,N-bis(2-hydroxy ethyl) linseed oil fatty
amide diol (HELA) with resorcinol. It was further treated with different percentage of toluylene 2-4-diisocyanate (TDI) to
obtain the urethane modified polyetheramide resins (UPEtA). The structural elucidation of PEtA and urethane modified polyetheramide(UPEtA)
were carried out by FT-IR, 1H-NMR and 13C-NMR spectroscopic techniques. These analyses confirm the formation of PEtA and UPEtA. Physico-chemical and physico-mechanical
analysis were performed by standard laboratory methods. The resin composition UPEtA-24 showed best physico-mechanical properties
with scratch hardness 2.0 kg, impact resistance 150 lb/in. and good bending ability. The thermal stability and curing behavior
of polymers were respectively studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Thermal
analysis shows that these coatings can be used safely upto 190 °C. The coatings of UPEtA resins were prepared on mild steel
strips. The anticorrosive behavior of UPEtA coatings were investigated in acid, alkali, water and xylene. All the coatings
exhibit good chemical resistance performance in acid, alkali, saline and organic solvents, while the resin UPEtA-24 shows
the best performance. |
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