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串联组合离子选择电极的研究——利用Ag2S电极测定废水中S2-离子含量
引用本文:陈兆鹏,张正奇,陈声宗,曹祉祥,吴来喜.串联组合离子选择电极的研究——利用Ag2S电极测定废水中S2-离子含量[J].环境科学,1991(6):34-36.
作者姓名:陈兆鹏  张正奇  陈声宗  曹祉祥  吴来喜
作者单位:湖南大学化学化工系 (陈兆鹏,张正奇,陈声宗,曹祉祥),湖南大学化学化工系(吴来喜)
摘    要:本文依据电池串联原理将多组电极串联组合,减少了因电动势测量误差而造成的测定浓度的相对误差,明显地提高了测定的精密度和准确度.对工业废水中S~(2-)离子含量的测定结果令人满意.其相对偏差低于2.5%,方法回收率为97.5—101.7%,明显优于现有离子选择电极测定方法.与比色法进行比较,测得结果基本一致.

关 键 词:电极串联组合  硫离子选择电极  硫离子含量

Investigation of Ion Selective-Electrodes by Series Combination--Determination of Sulfide Ion in Wagtewater with Silver Suifide Electrode.
Cheng Zhaopeng,Zhang Zhengqi,Chen Shengzong,Cao Zhixiang and Wu Laoxi.Investigation of Ion Selective-Electrodes by Series Combination--Determination of Sulfide Ion in Wagtewater with Silver Suifide Electrode.[J].Chinese Journal of Environmental Science,1991(6):34-36.
Authors:Cheng Zhaopeng  Zhang Zhengqi  Chen Shengzong  Cao Zhixiang and Wu Laoxi
Institution:Department of Chemistry and Chemical Engineering, Hunan University;Department of Chemistry and Chemical Engineering, Hunan University;Department of Chemistry and Chemical Engineering, Hunan University;Department of Chemistry and Chemical Engineering, Hunan University;Department of Chemistry and Chemical Engineering, Hunan University
Abstract:A group of silver sulfide electrode combined in series was applied to determine sulfide ion in wastewater. The experimental results show that the series combination of the electrodes greatly improved the accuracy and precision. The relative deviation is smaller than 2.5% and the recoveries arc in the range of 97.5-101.7%.
Keywords:Sulfide ion selective-electrode  sulfide ion    
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