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微波-改性活性炭-Fenton试剂氧化法降解水中2,4-二氯酚
引用本文:陈芳艳,肖洁,唐玉斌.微波-改性活性炭-Fenton试剂氧化法降解水中2,4-二氯酚[J].化工环保,2008,28(2).
作者姓名:陈芳艳  肖洁  唐玉斌
作者单位:江苏科技大学生物与环境工程学院,江苏,镇江,212018
基金项目:江苏省高校自然科学基础研究基金项目(07KJD6100518)
摘    要:以经Fe2(SO4)3溶液浸渍改性的活性炭作催化剂、Fenton试剂作氧化剂,采用微波-改性活性炭-Fenton试剂氧化法降解水中的2,4-二氯酚。考察了改性活性炭加入量、H2O2与Fe^2+摩尔比、Fenton试剂加入量、微波功率和2,4-二氯酚溶液初始pH对2,4-二氯酚降解效果的影响。在改性活性炭加入量1.0g/L、n(H2O2):n(Fe^2+)=16.7(H2O2加入量6.0mmol/L、Fe^2+加入量0.36mmol/L)、Fenton试剂加入量为6.36mmol/L、微波功率600W、微波辐射时间10min、2,4-二氯酚溶液初始pH为6.0的条件下,2,4-二氯酚降解率和TOC去除率分别可达98.7%和84.0%。

关 键 词:微波  Fenton试剂  降解  2  4-二氯酚  总有机碳  废水处理

Degradation of 2,4-Dichlophenol by Microwave-Modified Activated Carbon-Fenton Reagent Oxidation Process
Chen Fangyan,Xiao Jie,Tang Yubin.Degradation of 2,4-Dichlophenol by Microwave-Modified Activated Carbon-Fenton Reagent Oxidation Process[J].Environmental Protection of Chemical Industry,2008,28(2).
Authors:Chen Fangyan  Xiao Jie  Tang Yubin
Abstract:2,4-dichlophenol in water was degraded by microwave-modified activated carbon-Fenton reagent oxidation with activated carbon modified by dipping in Fe2(SO4)3 solution as catalyst and Fenton reagent as oxidant.The factors affecting the degradation of 2,4-dichlophenol were investigated.The experimental results show that: when modified activated carbon dosage is 1.0 g/L,n(H2O2):n(Fe2+)=16.7(H2O2 dosage 6.0 mmol/L and Fe2+ dosage 0.36 mmol/L),Fenton reagent dosage is 6.36 mmol/L,microwave power is 600 W,microwa...
Keywords:microwave  Fenton reagent  degradation  2  4-dichlophenol  total organic carbon  wastewater treatment  
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