Removal of nickel (II) from aqueous solutions using marine macroalgae as the sorbing biomass |
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Authors: | Kalyani S Srinivasa Rao P Krishnaiah A |
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Affiliation: | Department of Chemistry, Sri Venkateswara University, Tirupati 517 502, India. |
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Abstract: | In the present study biosorption technique, the passive accumulation of metals by biomass, is used for the removal of nickel from aqueous medium. The brown algae, Sargassum sp., in its natural and acid treated forms are used as a low cost sorbent. The adsorption characteristics of nickel on Sargassum sp. are evaluated as a function of time, pH, adsorbent dosage and initial concentration of nickel. The equilibrium adsorption data are fitted to Freundlich and Langmuir adsorption isotherm models and the model parameters are evaluated. Both the models represent the experimental data satisfactorily. The adsorption follows Lagergren first order kinetic model. The monolayer adsorption capacities of natural and acid treated forms of algae as obtained from Langmuir adsorption model are found to be 181 and 250mg g(-1) respectively. |
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