Phosphate adsorption performance of a novel filter substrate made from drinking water treatment residuals |
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Authors: | Wendong Wang Cui M Yinting Zhang Shengjiong Yang Yue Shao Xiaochang Wang |
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Institution: | 1 Department of Environmental and Municipal Engineering, Xi''an University of Architecture and Technology, Xi''an 710055, China.;2 Zhejiang Provincial Key Laboratory of Water Science and Technology, Zhejiang 314006, China;3 Department of Chemical and Biomolecular Engineering, Rice University, Houston 77005, USA |
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Abstract: | Phosphate is one of the most predominant pollutants in natural waters. Laboratory experiments were conducted to investigate the phosphate adsorption performance of a (NFS) made from drinking water treatment residuals. The adsorption of phosphate on the NFS fitted well with the Freundlich isotherm and pseudo second-order kinetic models. At pH 7.0, the maximum adsorption capacity of 1.03 mg/g was achieved at 15°C corresponding to the wastewater temperature in cold months, and increased notably to 1.31 mg/g at 35°C. Under both acidic conditions (part of the adsorption sites was consumed) and basic conditions (negative charges formed on the surface of NFS, which led to a static repulsion of PO43 − and HPO42 −), the adsorption of phosphate was slightly inhibited. Further study showed that part of the adsorption sites could be recovered by 0.25 mol/L NaOH. The activation energy was calculated to be above 8.0 kJ/mol, indicating that the adsorption of phosphate on NFS was probably a chemical process. Considering the strong phosphate adsorption capacity and recoverability, NFS showed great promise on enhancing phosphate removal from the secondary treated wastewater in the filtration process. |
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Keywords: | Adsorption Drinking water treatment residuals Domestic wastewater Filter substrate Phosphate |
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