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钒钛磁铁矿制备絮凝剂用于有机污水处理的研究
引用本文:颜海燕,张贤明,聂煜东,李金,申粤,耿媛媛. 钒钛磁铁矿制备絮凝剂用于有机污水处理的研究[J]. 环境污染与防治, 2022, 44(2): 190-194. DOI: 10.15985/j.cnki.1001-3865.2022.02.008
作者姓名:颜海燕  张贤明  聂煜东  李金  申粤  耿媛媛
作者单位:重庆工商大学废油资源化技术与装备教育部工程研究中心,重庆 400067
基金项目:重庆市科委科学研究项目(No.cstc2018jcyjAX0734);重庆市教委自然科学项目(No.KJ1600620);重庆市教委重大科技项目(No.KJZD-M201900802、No.KJZD-K201800801);重庆工商大学高层次人才启动项目(No.1856003);重庆工商大学重点平台开放项目(No.KFJJ2018064)。
摘    要:
以钒钛磁铁矿为原料,利用盐酸浸出工艺制备铁、钛、钒三元絮凝剂,对工艺条件进行优化后用于处理模拟有机污水,并与聚合氯化铁(PFC)的絮凝效果进行对比.结果表明:在浸出时间为4 h、浸出温度为80℃、液固质量比为5、盐酸初始质量分数为20%时,浸出效果最佳,钒、铁、钛的浸出率分别为99.98%、97.77%、10.41%;...

关 键 词:盐酸浸出工艺  钒钛磁铁矿  絮凝  有机污水

Study on preparation of vanadium-titanium magnetite flocculant for organic wastewater treatment
YAN Haiyan,ZHANG Xianming,NIE Yudong,LI Jin,SHEN Yue,GENG Yuanyuan. Study on preparation of vanadium-titanium magnetite flocculant for organic wastewater treatment[J]. Environmental Pollution & Control, 2022, 44(2): 190-194. DOI: 10.15985/j.cnki.1001-3865.2022.02.008
Authors:YAN Haiyan  ZHANG Xianming  NIE Yudong  LI Jin  SHEN Yue  GENG Yuanyuan
Affiliation:(Engineering Research Center of Waste Oil Recycling Technology and Equipment,Ministry of Education,Chongqing Technology and Business University,Chongqing 400067)
Abstract:
Taking vanadium-titanium magnetite as raw material,iron-titanium-vanadium ternary flocculant was prepared by hydrochloric acid leaching process.The hydrochloric acid leaching conditions were optimized and then the flocculant was used to treat simulated organic wastewater.And the results was compared with polymerization ferric chloride(PFC).Results showed that the optimal leaching conditions were leaching time of 4 h,leaching temperature of 80℃,liquid-solid mass ratio of 5,and hydrochloric acid initial mass percentage of 20%.The leaching rates of vanadium,iron and titanium reached 99.98%,97.77%and 10.41%,respectively.When the dosage of the flocculant(taking the sum of iron,vanadium and titanium mass concentrations)was 25 mg/L,the flocculants with or without alkalization both had the best treatment effect.At that time,the flocculants with or without alkalization had the turbidity removal rate of 97.01%and 98.02%,with the total organic carbon(TOC)removal rate of 82.20%and 81.64%,respectively.Moreover,the TOC removal rate of the ternary flocculants were better than that of PFC.The ternary flocculants were aslo turned out that they had good removal effect on dissolved microbial metabolites,humic acid and protein of dissolved orgainc matter.
Keywords:hydrochloric acid leaching process  vanadium-titanium magnetite  flocculation  organic wastewater
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