Ozone–dioxane delignification from the cell walls of Japanese cypress (Chamaecyparis obtusa Endl.) |
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Authors: | Shinso Yokota Kazuya Iizuka Futoshi Ishiguri Zensaku Abe Nobuo Yoshizawa |
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Institution: | (1) Forest Products, Department of Forest Science, Faculty of Agriculture, Utsunomiya University, Utsunomiya Tochigi, 321-8505, Japan |
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Abstract: | Delignification from the cell walls with a combination of ozone oxidation and dioxane–water extraction using thin sections
of a softwood, Japanese cypress (Chamaecyparis obtusa Endl.), was studied to determine its suitability for the production of recyclable cellulose-based materials from wood waste.
The visible-light absorption spectra of treated wood sections revealed that delignification from the cell walls with ozone
increased with increasing ozonization time. Ozone delignification proceeded from the lumen side toward the middle lamella
within the secondary wall of a cell, and it proceeded faster in early wood than in late wood within an annual ring. Mild ozonization
for 10–30 min was sufficient for the removal of lignin from the cell walls when sections were extracted with dioxane after
ozonization. The results obtained here demonstrate that microspectrometry coupled with the Wiesner reaction is useful for
the quantitative analysis of lignin in cell walls. |
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Keywords: | Ozonization Dioxane Lignin Cell wall Microspectrophotometry |
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