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The effect of EURO-0 vehicle substitution on polycyclic aromatic hydrocarbon and carbon monoxide concentrations in an urban area
Authors:Federico Valerio  Anna Stella  Mauro Pala  Daniele Balducci  Maria Teresa Piccardo  Massimo Cipolla
Institution:1. Department of Internal Medicine, Wake Forest School of Medicine, Winston-Salem, North Carolina;2. Section on Cardiology, Department of Internal Medicine, Wake Forest School of Medicine, Winston-Salem, North Carolina;3. Epidemiological Cardiology Research Center (EPICARE), Department of Epidemiology and Prevention, Wake Forest School of Medicine, Winston-Salem, North Carolina;1. Department of Safety and Radiation Protection, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany;2. Department of Radiation Oncology, RWTH Aachen University Hospital, D-52074 Aachen, Germany;1. Institute of Radiation Medicine, Chinese Academy of Medical Science and Peking Union Medical College, Tianjin 300192, PR China;2. Qianfoshan Hospital of Shandong Province, PR China;3. Radiation Medical Institute, Shandong Academy of Medical Sciences, Jinan 250062, PR China;4. Center of Disease Control and Prevention, Sichuan Province 610041, PR China;1. Sullivan Nicolaides Pathology, 134 Whitmore street, Taringa, Queensland 4068, Australia;2. School of Information Technology and Electrical Engineering, The University of Queensland, St Lucia, Queensland 4072, Australia;3. Department of Information Engineering, Electrical Engineering and Applied Mathematics, University of Salerno, Via Giovanni Paolo II, 132, Fisciano, SA I-84084, Italy;1. Department of Chemistry, University of São Paulo, Ribeirão Preto, SP 14040-901, Brazil;2. Institute of Chemistry, São Paulo State University, Araraquara, SP 14800-900, Brazil;3. Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, Portugal
Abstract:From 1994 to 2003, daily air concentrations of particle-bound polycyclic aromatic hydrocarbons (PAHs) and carbon monoxide (CO) were regularly monitored at two traffic-oriented sampling sites (A and B) in urban Genoa, Italy. The data were used to estimate effects on air quality in real situations due to progressive substitution of EURO-0 vehicles, started in 1993, with less-polluting vehicles (EURO-1, EURO-2), mainly gasoline vehicles with a catalyst. PAH profile classification and diagnostic PAH ratios were used to identify 345 samples of predominantly traffic origin. At both sites, CO and PAH daily concentrations decreased exponentially with time and the apparent half-life values calculated were 6.3 and 5.5 for CO and 3.7 and 3.5 years for PAHs at sites A and B, respectively. At site A, monitored for traffic intensity, multiple regression analyses confirmed that daily PAH and CO concentrations were positively correlated with the number of non-catalytic vehicles estimated to cross this site during sampling and negatively correlated with seasonal variables (air temperature, ozone concentration, relative air humidity). The reduction in air pollution estimated for complete substitution of non-catalytic gasoline vehicles was 89% for BaP, 85% for total PAHs and 69% for CO.
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