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几种萃取剂对土壤中重金属生物有效部分的萃取效果
引用本文:刘玉荣,党志,尚爱安,文震. 几种萃取剂对土壤中重金属生物有效部分的萃取效果[J]. 生态环境, 2002, 11(3): 245-247
作者姓名:刘玉荣  党志  尚爱安  文震
作者单位:1. 中国科学院地球化学研究所,环境地球化学国家重点实验室,贵州,贵阳,550002
2. 华南理工大学化工学院,广东,广州,510641
3. 华东理工大学环境工程系,上海,200237
基金项目:国家自然科学基金(49873033),广东省环保局项目(2001-27)
摘    要:采用6种萃取剂:pH=7的0.01mol/L CaCl_2、pH=7.3的0.005mol/L DTPA+0.1mol/L TEA(三乙醇胺)+0.01mol/L CaCl_2O.1mol/L NaNO_3、0.43mol/L HOAc、pH=7的0.05mol/L EDTA和pH=4.65的0.5mol/L NH_4OAc+0.02mol/L EDTA浸取液.对污染土壤中的重金属Cu、Zn、Cd、Pb、的进行了萃取,并比较了萃取剂的萃取能力。实验结果表明,HOAc、EDTA以及NH_4OAc-EDTA萃取各种重金属的能力远远大于其它几种萃取剂的萃取能力,是比较理想的萃取剂。

关 键 词:重金属  化学萃取法  生物有效性
文章编号:1008-181X(2002)03-0245-03
修稿时间:2001-10-16

Comparing several extractants for extracting bioavailable part of heavy metals in soils
LIU Yu-rong,DANG Zhi,SHANG Ai-an,WEN Zhen: State Key Laboratory of Environmental Geochemistry. Comparing several extractants for extracting bioavailable part of heavy metals in soils[J]. Ecology and Environmnet, 2002, 11(3): 245-247
Authors:LIU Yu-rong  DANG Zhi  SHANG Ai-an  WEN Zhen: State Key Laboratory of Environmental Geochemistry
Affiliation:LIU Yu-rong,DANG Zhi,SHANG Ai-an,WEN Zhen1: State Key Laboratory of Environmental Geochemistry,Institute of Geochemistry,Guiyang 550002,China, 2: Department of Applied Chemistry,South China University of Technology,Guangzhou 510640,China, 3: Department of Environmental Engineering,East China University of Technology,Shanghai 200237,China
Abstract:Heavy metals were extracted with six selected solutions and the extraction results were compared .The six solutions were : 0.01 mol/L CaCl2 (pH=7), 0.005 mol/L DTPA+0.1 mol/L TEA+0.01 mol/L CaCl2(pH=7.3), 0.1 mol/L NaNO3, 0.43 mol/L HOAc, pH=7 0.05 mol/L EDTA( pH=7) and 0.5 mol/L NH4OAc+0.02 mol/L EDTA( pH=4.65). It was showed that the extraction results of HOAc, EDTA and NH4OAc-EDTA were much better than other extractants, and they were suitable to extract the bio-effective parts of heavy metals in soils .
Keywords:heavy metal  bioavailability  chemical extraction solution
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