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Preparation and characterization of activated carbon foam from phenolic resin
Authors:Xuefei ZHAO  Shiquan LAI  Hongzha LIU  Lijuan GAO
Institution:1. School of Materials Science and Engineering, East China University of Science and Technology, Mei Long Road 130, Shanghai 200237, P.R. China;2. Guotai Huarong New Chemical Materials Co. Ltd., Chengdong Road 112, Zhangjiagang 215634, P.R. China;1. Programa de Pós-graduação em Ciência e Engenharia de Materiais (PPGCEM), Laboratório de Peneiras Moleculares (LABPEMOL), Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN, Brasil;2. Laboratorio de Sólidos Porosos (LabSoP), Instituto de Física Aplicada (INFAP-CONICET), Universidad Nacional de San Luis (UNSL), San Luis, Argentina;1. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, PR China;2. Research Institute of Chemical Defense, Beijing 100091, PR China
Abstract:Activated carbon foam was successfully prepared from phenolic resin synthesized with phenol and formaldehyde under alkali condition. The influence of process variables, such as steam rate, carbonization temperature, carbonization time, activation temperature and activation time on the adsorption capacities of the activated carbon foam was studied. Under the optimum experimental conditions, the activated carbon foam with a specific surface area 727.62 m2/g was obtained. Moreover, the iodine value and carbon tetrachloride value of the activated carbon foam was 1050.28 mg/g and 401.37 mg/g, respectively. The pore size of the activated carbon foam was in the range of 3.5–5 nm which was determined through the N2 adsorption test. In addition, the yield of the activated carbon foam was 36.24%. The result of scanning electron microscopy (SEM) showed that the activated carbon foam became honeycomb structure, and its pore wall was thinner and smoother compared to the unactivated carbon foam.
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