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Removal of copper ions from aqueous solution by calcium alginateimmobilized kaolin
Authors:Yanhui Li  Bing Xi  Quansheng Zhao  Fuqiang Liu  Pan Zhang  Qiuju Du  Dechang Wang  Da Li  Zonghua Wang  Yanzhi Xia
Affiliation:1. Laboratory of Fiber Materials and Modern Textile,The Growing Base for State Key Laboratory,Qingdao University,Qingdao 266071,China
2. Laboratory of Fiber Materials and Modern Textile,The Growing Base for State Key Laboratory,Qingdao University,Qingdao 266071,China;Department of Environmental Science and Engineering,Qingdao University,Qingdao 266071,China
3. Department of Environmental Science and Engineering,Qingdao University,Qingdao 266071,China
Abstract:
Kaolin has been widely used as an adsorbent to remove heavy metal ions from aqueous solutions. However, the lower heavy metaladsorption capacity of kaolin limits its practical application. A novel environmental friendly material, calcium alginate immobilizedkaolin (kaolin/CA), was prepared using a sol-gel method. The e ects of contact time, pH, adsorbent dose, and temperature on Cu2+adsorption by kaolin/CA were investigated. The Langmuir isotherm was used to describe the experimental adsorption, the maximumCu2+ adsorption capacity of the kaolin/CA reached up to 53.63 mg/g. The thermodynamic studies showed that the adsorption reactionwas a spontaneous and endothermic process.
Keywords:kaolin   calcium alginate   copper   adsorption, immobilization
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