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淀粉-g-丙烯酸/凹凸棒土复合物制备及其吸附废水中NH_4~+-N性能
引用本文:陆蓓蓓,冯杨阳,陈英文,沈树宝.淀粉-g-丙烯酸/凹凸棒土复合物制备及其吸附废水中NH_4~+-N性能[J].环境污染治理技术与设备,2011(10):2173-2176.
作者姓名:陆蓓蓓  冯杨阳  陈英文  沈树宝
作者单位:南京工业大学生物与制药工程学院,南京210009
基金项目:国家高技术研究发展计划(863)项目(2009AA05Z313); 国家自然科学基金项目(50872052); 国家“水专项”课题(2008ZX07101-003-02-05); 江苏省环保课题(2009002)
摘    要:采用反相乳液聚合法以凹凸棒土为原料,合成了新型NH4+-N吸附剂淀粉-g-丙烯酸/凹凸棒土,并进行了氨氮吸附对比实验。结果表明:凹凸棒土氨氮单位吸附量为4.243 mg/g;淀粉-g-丙烯酸/凹凸棒土氨氮单位吸附量为5.301 mg/g,吸附能力比未改性的凹凸棒土提高了25%。淀粉-g-丙烯酸/凹凸棒土的氨氮吸附过程比凹凸棒土更符合Freundlich等温吸附模型。随着pH、温度的升高,凹凸棒土和淀粉-g-丙烯酸/凹凸棒土对NH4+-N吸附量逐渐增大。

关 键 词:反相乳液  淀粉-g-丙烯酸/凹凸棒土  氨氮  吸附

Synthesis of starch-g-AA/attapulgite and adsorption of NH_4~+-N in wastewater
Lu Beibei Feng Yangyang Chen Yingwen Shen Shubao.Synthesis of starch-g-AA/attapulgite and adsorption of NH_4~+-N in wastewater[J].Techniques and Equipment for Environmental Pollution Control,2011(10):2173-2176.
Authors:Lu Beibei Feng Yangyang Chen Yingwen Shen Shubao
Institution:Lu Beibei Feng Yangyang Chen Yingwen Shen Shubao (College of Biotechnology and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 210009,China)
Abstract:A novel composite adsorbent based on starch and attapulgite for removing NH+4-N in wastewater was prepared by inverse emulsion polymerization,and comparison of ammonia nitrogen adsorption tests was carried out.The results showed that the adsorption capacity of unmodified attapulgite was 4.243 mg/g,while the adsorption capacity of starch-g-AA/attapulgite at 5.301 mg/g which was higher than the unmodified attapulgite by 25%.Adsorption process of starch-g-AA/attapulgite fitted Freundlich isotherm equation better than that of attapulgite.With the increase of pH and temperature,NH+4-N adsorption capacity of both attapulgite and starch-g-AA/attapulgite increased.
Keywords:inverse emulsion  starch-g-AA/attapulgite  ammonia nitrogen  adsorption
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