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Ni/Ce-Y沸石的制备及其对二苯并噻吩吸附研究
引用本文:王娟,徐芳,曾辉,张秋卓,张海波,蔡伟民.Ni/Ce-Y沸石的制备及其对二苯并噻吩吸附研究[J].环境科学与技术,2008,31(9).
作者姓名:王娟  徐芳  曾辉  张秋卓  张海波  蔡伟民
作者单位:1. 哈尔滨工业大学市政环境工程学院,黑龙江,哈尔滨,150090
2. 上海交通大学环境科学与工程学院,上海,200240
3. 哈尔滨工业大学市政环境工程学院,黑龙江,哈尔滨,150090;上海交通大学环境科学与工程学院,上海,200240
摘    要:研究了负载二元金属NiCe-Y沸石的制备以及吸附二苯并噻吩的动力学性能。试验考察了二元金属Ni、Ce离子交换顺序、负载溶液方面对吸附剂制备的影响,初步得到了制备负载二元金属NiCe-Y吸附剂的优化条件。对NiCe-Y吸附剂进行脱硫性能评价及动力学分析,结果表明,负载二元金属NiCe-Y吸附剂比负载单一金属的Ni-Y吸附量提高31%,比Ce-Y吸附剂提高16%。

关 键 词:NiCe-Y沸石  二苯并噻吩  吸附

Preparation of Ni/Ce-Y Zeolites and Its Adsorption Removal for Dibenzothiophene
WANG Juan,XU Fang,ZENG Hui,ZHANG Qiu-zhuo,ZHANG Hai-bo,CAI Wei-min.Preparation of Ni/Ce-Y Zeolites and Its Adsorption Removal for Dibenzothiophene[J].Environmental Science and Technology,2008,31(9).
Authors:WANG Juan  XU Fang  ZENG Hui  ZHANG Qiu-zhuo  ZHANG Hai-bo  CAI Wei-min
Abstract:Preparation of binary Y zeolites loading Ni and Ce ions and its adsorption kinetics for dibenzothiophene were studied. Effect of exchanging order of bimetal and exchange solution on preparation of NiCe-Y zeolites was examined and preparation conditions were optimized. Adsorption properties and kinetic analysis for removal of dibenzothiophene from model oil on binary Y zeolites loading Ni and Ce ions were studied, results indicated that adsorption capacity of NiCe-Y zeolites was 31% higher than that of Ni-Y zeolites and 16% higher than Ce-Y zeolites.
Keywords:binary Y zeolites loading Ni and Ce ions  dibenzothiophene  adsorption
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