低温热水解和超声联合破解污泥优化工艺的参数研究

针对国内低温热水解和超声联合技术应用于低有机质剩余污泥厌氧消化预处理领域的实验研究和工艺参数缺陷问题,探讨了低于100℃的低温热水解和超声波技术联合破解剩余污泥的技术可行性及工艺参数的优化.以热水解温度和超声能量为控制参数,以污泥破解度、溶解性蛋白质和多糖浓度为分析指标,通过Box-Behnken设计实验,并根据响应曲面法(RSM)构建了污泥破解的二次多项式预测模型,进而得到各影响因素作用下的最佳破解工艺参数.结果表明,温度对污泥破解的影响较超声能量明显.低温热水解和超声联合作用下,最佳工艺组合为温度80℃和超声能量12000kJ/kgTS,该工艺下的污泥破解结果为污泥破解度39.01%,溶解性蛋白质1360.59mg/L和多糖334.52mg/L,该结果与预测值吻合度较高,表明响应曲面模型所得参数较为可靠,能够为实际应用和推广提供参考.

Optimizing parameters of sludge disruption by combined low temperature thermal and ultrasonic pretreatment through response surface methodology

The scientific gap of operating parameters of combined thermal and ultrasonic disintegration at low temperature of waste activated sludge(WAS) still needs to be filled. This study provides more insights into the technical feasibility of low organic WAS disruption pretreated by combined thermal at temperature lower than 100℃ and ultrasonic technique. Optimization of combined thermal and ultrasonic disintegration of WAS for enhanced organic releasing was carried out using response surface methodology(RSM) and Box-Behnken design of experiment. The quadratic effects as well as the interactive effects of temperature and specific energy on the disintegration degree of SCOD, soluble concentration of protein and carbohydrate were investigated. Results indicated that quadratic effect of temperature was more significant in affecting sludge disintegration than specific energy and regression models had good fitness with experimental results. The optimum disintegration degree of SCOD, soluble concentration of protein and carbohydrate achieved were 39.01%, 1360.59mg/L and 334.52mg/L, respectively, at 80℃ and 12000kJ/kg TS. In addition, the verification experiments appeared high coincide degree with predicted results, indicating that the models were reliable for application and promotion of combined thermal and ultrasonic disintegration.