温度对城市有机垃圾热解焦油成分的影响

以城市有机垃圾热解焦油为对象,研究了不同热解终温下(600~800℃)焦油的特性及其随温度的变化规律.结果表明:随着热解终温从600℃升高至800℃,焦油中C含量从74.49%增至83.42%;焦油的芳香化程度高于原料而低于热解炭,焦油的极性低于原料和热解炭,随着热解终温的升高,焦油的H/C和O/C逐渐降低;多环芳烃(PAHs)是焦油的主要成分,随着热解终温从600℃升高至800℃,其含量从54.06%增至83.45%;萘及其衍生物是焦油PAHs的主要成分,其含量在热解终温600、700、800℃时分别占PAHs的50.72%、46.80%、39.26%.研究结果证明了垃圾热解焦油可用作碳基复合材料和作为制备染料、树脂、溶剂、驱虫剂等的原料.

Effect of temperature on composition of tar generated from pyrolysis of organic fraction of municipal solid waste

A series of batch experiments were performed to characterize the composition change of tars generated from pyrolysis of organic fraction of municipal solid waste (OFMSW) at the final pyrolysis temperatures of 600, 700 and 800℃, respectively. The carbon content in the tars increased from 74.49% to 83.42% with the pyrolysis temperature increased from 600 to 800℃. Although the aromaticity of tars was higher than OFMSW and lower than chars, the polarity of tars was lower than both OFMSW and chars. Decreases in H/C and O/C ratios in tars were observed with the increase in final pyrolysis temperature. The content of polycyclic aromatic hydrocarbons (PAHs), the dominant components of tars, increased from 54.06% to 83.45% when the pyrolysis temperature rose from 600 to 800°C. Naphthalene and its derivatives were main components of PAHs, and they accounted for 50.72%, 46.80% and 39.26% of total PAHs in tars that were obtained at 600, 700, 800℃, respectively. The pyrolysis tars generated from OFMSW could be utilized as carbon based matrix composites and the raw materials for the production of dyes, resins, solvents, and insect repellents, etc.