Recovery of methyl orange and Congo red from aqueous solutions using tri-octyl amine (TOA) in benzene as carrier |
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| Institution: | 1. Department of Mining Engineering, Faculty of Engineering, University of Birjand, Birjand, Iran;2. Department of Mining Engineering, Faculty of Engineering, University of Birjand, Birjand, Iran;3. Department of Mining Engineering, Isfahan University of Technology, Isfahan, Iran;1. Chemical Engineering Department, Khalifa University of Science and Technology, Masdar City Campus, P. O. Box 54224, Abu Dhabi, United Arab Emirates;2. Department of Chemical Engineering, King Saud University, Riyadh, Saudi Arabia |
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| Abstract: | The recovery of anionic azo dyes namely Congo red (CR), methyl orange (MO) from acidic aqueous solutions using tri-octyl amine (TOA) as an extractant has been investigated. The percentage of extraction of MO and CR increases with an increasing TOA concentration. The anionic dyes were extracted from aqueous solution at pH 2.0 ± 0.1. The extracted dye has been back extracted into aqueous solutions using sodium hydroxide, sodium carbonate and sodium bicarbonate. The organic phase obtained after the stripping of dyes was washed with dilute sodium hydroxide solution to neutralize any sulphuric acid trapped or adhered to the solvent and then with distilled water. This solvent was reused in succeeding extraction of dyes. The influencing parameters were; the effect of diluents, effect of extractant concentration, effect of pH, effect of interference study, effect of equilibrium time, various stripping reagents and stripping phase ratio. The characterization studies such as UV and IR spectra of extracted and stripped MO and CR was also studied. |
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| Keywords: | Extractant Trioctyl amine Stripping Methyl orange Characterization |
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