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Flower-, wire-, and sheet-like MnO2-deposited diatomites: Highly efficient absorbents for the removal of Cr(VI)
Authors:Yucheng Du  Liping Wang  Jinshu Wang  Guangwei Zheng  Junshu Wu  Hongxing Dai
Affiliation:Key Lab of Advanced FunctionalMaterials,Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China,Key Lab of Advanced FunctionalMaterials,Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China,Key Lab of Advanced FunctionalMaterials,Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China,Key Lab of Advanced FunctionalMaterials,Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China,Key Lab of Advanced FunctionalMaterials,Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China and Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
Abstract:Flower-, wire-, and sheet-like MnO2-deposited diatomites have been prepared using a hydrothermal method with Mn(Ac)2, KMnO4 and/or MnSO4 as Mn source and diatomite as support. Physical properties of the materials were characterized by means of numerous analytical techniques, and their behaviors in the adsorption of chromium(VI) were evaluated. It is shown that the MnO2-deposited diatomite samples with different morphologies possessed high surface areas and abundant surface hydroxyl groups (especially the wire-like MnO2/diatomite sample). Thewire-like MnO2/diatomite sample showed the best performance in the removal of Cr(VI), giving the maximum Cr(VI) adsorption capacity of 101 mg/g.
Keywords:Morphological effect  MnO2-deposited diatomite  Cr(VI) removal  Adsorption efficiency
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