Stable and eco-friendly solid acids as alternative to sulfuric acid in the liquid phase nitration of toluene |
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Institution: | 1. Department of Advanced Material Science & Engineering, Institute of Rare Metal, Mokpo National University, Chonnam 534-729, Republic of Korea;2. Division of Minerals Utilization and Materials, Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejon 305-350, Republic of Korea |
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Abstract: | Liquid-phase nitration of toluene was carried out using a silica supported Cs salt of phosphomolybdic acid (Cs2.5H0.5PMoO40) as catalyst with dilute nitric acid under mild conditions. The Cs2.5H0.5PMoO40 particles with Keggin-type structure were well dispersed on the surface of silica, and the catalysts exhibited strong acidity, which may be responsible for the high catalytic nitration activity. The effects of various parameters on nitration were tested, which included reaction temperature, reaction time, catalyst amount and reactants ratio. Under suitable conditions, the nitrations gave high toluene conversion (99.6%) and good mono-nitration selectivity. Compared to the conventional process, there was no other organic solvent or sulfuric acid used in the reaction system, which made it more environment-friendly. Moreover, the supported catalyst was proven to have excellent stability in the nitration process. |
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Keywords: | Liquid-phase nitration Toluene Solid acid Catalysis Supported |
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