| 高效液相色谱-电喷雾电离质谱法测定地表水中微囊藻毒素 |
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| 引用本文： | 宋俊密,丁海霞,段爱玲,张国祯,寇力斐.高效液相色谱-电喷雾电离质谱法测定地表水中微囊藻毒素[J].环境监测管理与技术,2011,23(6):65-67. |
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| 作者姓名： | 宋俊密 丁海霞 段爱玲 张国祯 寇力斐 |
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| 作者单位： | 甘肃省环境监测中心站,甘肃兰州730020 |
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| 摘 要： | 采用固相萃取-高效液相色谱-电喷雾电离质谱法测定饮用水源地地表水中痕量微囊藻毒素MC-LR,优化了色谱和质谱条件,以甲醇/水(含0.1％甲酸)混合溶液(体积比60:40)为流动相,选择定量离子质荷比(m/z)996.3.方法在0.100 mg/L-2.00 mg/L范围内线性良好,检出限为0.02 μg/L,空白水样加...
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| 关 键 词： | 微囊藻毒素-LR 固相萃取 高效液相色谱-电喷雾电离质谱 地表水 |
Determination of MC-LR in Surface Water by High Performance Liquid Chromatography with Mass Spectrometry |
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| SONG Jun-mi,DING Hai-xia,DUAN Ai-ling,ZHANG Guo-zhen,KOU Li-fei.Determination of MC-LR in Surface Water by High Performance Liquid Chromatography with Mass Spectrometry[J].The Administration and Technique of Environmental Monitoring,2011,23(6):65-67. |
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| Authors: | SONG Jun-mi DING Hai-xia DUAN Ai-ling ZHANG Guo-zhen KOU Li-fei |
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| Institution: | (Gansu Province Environmental Monitoring Center,Lanzhou,Gansu 730020,China) |
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| Abstract: | Trace Microcystin（MC-LR） in drinking source surface water was determined by HPLC-ESI-MS with solid phase extraction and test conditions of chromatography and mass was optimized.The results showed that mobile solution V（methanol）∶V（water）=60∶40] which contained 0.1% methanoic acid,selective quantity ion（m/z=996.3）.Good linearity of the method was obtained in range from 0.100 mg/L to 2.00 mg/L,the detection limits 0.02 μg/L,spiked standard recoveries of blank samples（96.2±5.4）%. |
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| Keywords: | MC-LR Solid phase extraction HPLC-ESI-MS Surface water |
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