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CO对定电位电解法测定SO2的影响及对策探讨
引用本文:张迪生.CO对定电位电解法测定SO2的影响及对策探讨[J].环境监测管理与技术,2014,26(2):60-62.
作者姓名:张迪生
作者单位:南京市环境监测中心站
基金项目:中国环境监测总站转型基金资助项目(CNEMC-ZXKY2009-032)
摘    要:采用定电位电解法测定固定污染源废气中SO2,根据CO标准气体干扰SO2 测定的规律建立数学模型,并在实验室用CO标气对数学模型进行验证.用该数学模型对5家企业固定污染源废气中SO2 监测,将测定结果与碘量法的测定结果比对,绝对误差与相对误差在允许范围内.

关 键 词:SO2  CO干扰  定电位电解法  数学模型  修正补偿

Influence of Carbon Monoxide on the Determination of Sulfur Dioxide by Constant Potential Electrolysis Method and Countermeasure Research
ZHANG Di-sheng,XIE Xin.Influence of Carbon Monoxide on the Determination of Sulfur Dioxide by Constant Potential Electrolysis Method and Countermeasure Research[J].The Administration and Technique of Environmental Monitoring,2014,26(2):60-62.
Authors:ZHANG Di-sheng  XIE Xin
Institution:( Nanjing Environmental Monitoring Center, Nanjing , Jiangsu 210013, China)
Abstract:SO2 from stationary sources was determined using the constant potential electrolysis method. A numerical model was established according to the rule of standard CO gas interference, and verification was done in the laboratory through preparation of CO standard gases. The numerical model was applied to monitor SO2 from five enterprises' stationary sources. The absolute error and relative error between the current method and the iodine titration method were within the acceptance scope.
Keywords:SO2  CO2 interference  Fixed potential by electrolysis method  Mathematical model  Modifying compensation
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