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Determination of Endosulfans in Soil/Sediment Samples from Point Mugu, Oxnard, California Using Capillary Gas Chromatography/Mass Selective Detection (GC/MSD)
Authors:Angela M Leung  D Matthew McDonough  C David West
Institution:(1) Department of Chemistry, Occidental College, 1600 Campus Road, Los Angeles, California, 90041, U.S.A
Abstract:The extent of contamination by endosulfans in soil samples collected from the Point Mugu watershed near Oxnard, California was determined using capillary gas chromatography/mass selective detection (GC/MSD). The study was designed to detect three organochlorinated pesticides: endosulfan agr, endosulfan beta and endosulfan sulfate. Thirteen sets of two soil samples each were taken from various sites in the region. Our results show that the endosulfan levels in these soils range from trace amounts to nearly 30 ppm, with endosulfan agr being the most abundant and endosulfan sulfate the least. Two sites of the study, Hueneme and Revolon and Farm and Revolon, showed high amounts of endosulfans agr and beta, with concentrations between 20 and 30 ppm. The majority of the other sites studied in this research produced concentrations of less than 10 ppm for each of the three endosulfans monitored. At five areas in particular, Pleasant Valley and Creek, Laguna and Creek, Etting and Creek, Road and Creek and Hueneme and Creek, less than 2 ppm or only trace amounts of endosulfans agr, beta and sulfate were detected.
Keywords:endosulfans  environmental contamination  pesticides  sediments  soils
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