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Dynamic Modeling of the Ratio Volatile Fatty Acids/Bicarbonate Alkalinity in a UASB Reactor for Potato Processing Wastewater Treatment
Authors:E M P Barampouti  S T Mai  A G Vlyssides
Institution:(1) National Technical University of Athens, Chemical Engineering School, 9, Heroon Polytechniou Street, Zographou, Greece
Abstract:In this work, dynamic mathematical model for the prediction of the operational parameter volatile fatty acids/bicarbonate alkalinity (VFA/ALK) in a UASB reactor was developed. The dynamic modeling technique was applied successfully to a two-year data record from an industrial wastewater treatment plant of a potato processing industry. The technique used included regression analysis by residuals. Seventeen parameters were examined including the following: wastewater's flow rate, reactor's temperature and pH, total and soluble influent COD, wastewater's temperature and pH, total and soluble effluent COD, volatile fatty acids, alkalinity, biogas production rate and each parameter with a time lag of up to 10 days. Finally, after all parameters and all time lag trials the best fitted model was developed. The model's adequacy was checked by χ2 test for a data record of the same UASB reactor but at a different time period and proved to be satisfactory. Additionally, the model's ability to predict and to control the plant's operation via VFA/ALK was examined. Through this model, in contrary to steady state models, various aspects of the process can be enlighten, such as the fact that the hydrolysis of starch requires at least a resident time of seven days.
Keywords:alkalinity  anaerobic digestion  dynamic model  potato processing wastewater  volatile fatty acids  upflow anaerobic sludge blanket
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