| PM2.5中丙二醛的检测、浓度特征及氧化损伤的研究 |
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| 引用本文： | 玉散&#;吐拉甫,迪丽努尔&#;塔力甫,苏吾比努尔&#;热克甫,图尔贡&#;艾尔肯,阿布力克木&#;阿不力孜,买丽克扎提&#;买合木提,亚力昆江&#;吐尔逊,米吉提&#;依明.PM2.5中丙二醛的检测、浓度特征及氧化损伤的研究[J].中国环境监测,2019,35(1):44-50. |
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| 作者姓名： | 玉散&#;吐拉甫 迪丽努尔&#;塔力甫 苏吾比努尔&#;热克甫 图尔贡&#;艾尔肯 阿布力克木&#;阿不力孜 买丽克扎提&#;买合木提 亚力昆江&#;吐尔逊 米吉提&#;依明 |
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| 作者单位： | 新疆大学煤炭清洁转化与化工过程自治区重点实验室;和田地区环境监测站 |
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| 基金项目： | 国家自然科学基金资助项目（41465007）；有机地球化学国家重点实验室项目（SKLOG-2016201624） |
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| 摘 要： | 以和田市城区2014年采集的大气PM_(2.5)样品为实验对象,将0.1 g的PM_(2.5)样品膜与2-硫代巴比妥酸(0.2%)和三氯乙酸(20%)混合显色液反应,用可见光分光光度计测定反应产物的吸光度,通过正交实验来优化PM_(2.5)膜中丙二醛(MDA)的提取及测定条件,结果表明,在反应温度90℃、超声和加热时间40 min、显色剂用量为45 mL时,反应产物在532 nm处具有稳定的最大吸收峰。对和田市城区PM_(2.5)及MDA质量浓度的变化特征分析结果表明,和田市城区4个季节PM_(2.5)平均质量浓度由高到低顺序分别为春季(1 096.67±369.60)μg/m~3、夏季(1 016.16±708.00)μg/m~3、秋季(686.88±525.00)μg/m~3和冬季(214.54±94.70)μg/m~3。MDA平均质量浓度的变化范围为1.10～7.75 ng/m~3,其平均值最高为夏季(4.43±1.80)ng/m~3,最低为春季(1.42±0.60)ng/m~3,冬季与秋季相当,分别为(2.93±0.70)ng/m~3和(2.83±0.80)ng/m~3;最终,将PM_(2.5)膜中MDA的质量浓度与相应的TD_(30)(体外DNA氧化损伤达到30%的剂量)进行相关性分析得出,无论是全样还是水样的TD_(30)值均随MDA浓度的升高而呈降低的趋势。其中,全样与MDA质量浓度的相关性更为显著(r=-0.597,显著性P0.01)。
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| 关 键 词： | PM2.5 和田 丙二醛 氧化损伤 |
| 收稿时间： | 2017/10/19 0:00:00 |
| 修稿时间： | 2017/12/28 0:00:00 |
Detection, Seasonal Characteristics and Oxidative Damage of Malondialdehyde in PM2.5 |
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| TURAP Yusan,TALIFU Dilinuer,REKEFU Suwubinuer,AIERKEN Tuergong,ABULIZI Abulikemu,MAIHEMUTI Mailikezhati,TUERSUN Yalikunjiang and YIMING Mijit.Detection, Seasonal Characteristics and Oxidative Damage of Malondialdehyde in PM2.5[J].Environmental Monitoring in China,2019,35(1):44-50. |
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| Authors: | TURAP Yusan TALIFU Dilinuer REKEFU Suwubinuer AIERKEN Tuergong ABULIZI Abulikemu MAIHEMUTI Mailikezhati TUERSUN Yalikunjiang and YIMING Mijit |
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| Institution: | Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China,Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China and Environmental Monitoring Station, Hetian 848000, China |
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| Abstract: | |
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| Keywords: | PM2 5 Hetian MDA oxidative damage |
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