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| 高效液相色谱-串联质谱法分析水体中六溴环十二烷异构体 | |
| 引用本文： | 李永东,云霞,那广水,王艳洁,方小丹,龙锦林,高会,姚子伟.高效液相色谱-串联质谱法分析水体中六溴环十二烷异构体[J].中国环境监测,2013,29(1):93-97. |
| 作者姓名： | 李永东 云霞 那广水 王艳洁 方小丹 龙锦林 高会 姚子伟 |
| 作者单位： | 1. 大连工业大学生物工程学院,辽宁大连116034;国家海洋环境监测中心国家海洋局近岸海域生态环境重点实验室,辽宁大连116023;济南市质量技术监督局食品质量监督检验中心,山东济南250002 2. 大连工业大学生物工程学院,辽宁大连,116034 3. 济南市质量技术监督局食品质量监督检验中心,山东济南,250002 |
| 基金项目： | 国家海洋局青年科学基金资助项目(20090507);海洋公益性项目(201105013) |
| 摘 要： | 建立了高效液相色谱-串联质谱(HPLC-MS-MS)准确测定水体中六溴环十二烷(HBCD)3种异构体(α-HBCD、β-HBCD、y-HBCD)残留量的方法.样品添加13C-HBCD后,以二氯甲烷液液萃取,萃取液经硅胶柱净化后,以甲醇-0.2％氨水溶液为流动相通过BDS-C18色谱柱进行分离,采用电喷雾电离(ESI)、负离子模式对HBCD异构体进行分析.该方法线性范围为0.5 ～ 100 μg/L,α-HBCD、β-HBCD、γ-HBCD 3种异构体检出限分别为0.42、0.52、0.48 ng/L,平均回收率分别为88％、84％、86％,相对标准偏差均小于6.5％.应用该法对黄海沿岸21个采样站位水样进行分析,其中13个采样站位有HBCD 3种异构体的检出,表明该法适用于水体中HBCD的检测. |
| 关 键 词： | 六溴环十二烷 固相萃取 高效液相色谱-串联质谱 黄海沿岸水体 |
| 收稿时间： | 6/8/2011 12:00:00 AM |
| 修稿时间： | 2011/9/23 0:00:00 |
Determination of Hexabromocyclododecane Isomers in Water by High Performance Liquid Chromatography-Tandem Mass Spectrometry |
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| LI Yong-dong,YUN Xi,NA Guang-shui,WANG Yan-jie,FANG Xiao-dan,LONG Jin-lin,GAO Hui and YAO Zi-wei.Determination of Hexabromocyclododecane Isomers in Water by High Performance Liquid Chromatography-Tandem Mass Spectrometry[J].Environmental Monitoring in China,2013,29(1):93-97. | |
| Authors: | LI Yong-dong YUN Xi NA Guang-shui WANG Yan-jie FANG Xiao-dan LONG Jin-lin GAO Hui and YAO Zi-wei |
| Institution: | Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;Key Laboratory for Ecological Environment in Coastal Areas (SOA),National Marine Environmental Monitoring Centre, Dalian 116023, China;The Supervision and Test Center of Foodstuff Quality, Jinan Supervisory Bureau of Quality& Technology, Jinan 250002, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;The Supervision and Test Center of Foodstuff Quality, Jinan Supervisory Bureau of Quality& Technology, Jinan 250002, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China;Biological Engineering School of Dalian Polytechnic University, Dalian 116034, China |
| Abstract: | |
| Keywords: | hexabromocyclododecane solid phase extraction HPLC-MS-MS Yellow sea water |
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