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BDE-47在土壤矿物质与有机质上的吸附解吸特征
引用本文:张美芳,樊孝俊.BDE-47在土壤矿物质与有机质上的吸附解吸特征[J].中国环境监测,2015,31(4):82-85.
作者姓名:张美芳  樊孝俊
作者单位:南昌市环境监测站,江西 南昌,330038
摘    要:以多溴联苯醚典型单体2,2′,4,4′?四溴联苯醚(BDE?47)为研究对象,阐明了其在土壤矿物质与有机质上的吸附解吸行为及特征。结果表明:土壤中无机矿物质对BDE?47的吸附贡献不大,而有机质是调控BDE?47在土壤中吸附行为的关键组分;有机质对BDE?47的吸附能力与其有机碳含量和物理化学特性相关;BDE?47在腐殖酸上的解吸存在显著的滞后现象。

关 键 词:BDE-47  土壤  吸附  解吸  滞后
收稿时间:2014/10/29 0:00:00
修稿时间:2014/12/23 0:00:00

Studied on Sorption-Desorption Characteristics of BDE-47 in Soil Minerals and Organic Matter
ZHANG Mei-fang and FAN Xiao-jun.Studied on Sorption-Desorption Characteristics of BDE-47 in Soil Minerals and Organic Matter[J].Environmental Monitoring in China,2015,31(4):82-85.
Authors:ZHANG Mei-fang and FAN Xiao-jun
Institution:Nanchang Environmental Monitoring Station, Nanchang 330038, China and Nanchang Environmental Monitoring Station, Nanchang 330038, China
Abstract:In this study,we used 2,2',4,4'-tetrabromodiphenyl ether (BDE-47) as a model compound to elucidate the sorption-desorption behavior and characteristics of PBDEs in soil minerals and organic matter. The experimental results indicated that: inorganic minerals in soil sorb little BDE-47,while organic matter is the key component that regulate the sorption behavior of BDE-47 in soil; the sorption capacity of organic matter sorb BDE-47 is related to its organic carbon content and physical-chemical properties; desorption of BDE-47 from humic acids exhibits significant hysteresis.
Keywords:BDE-47  soil  sorption  desorption  hysteresis
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