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Experimental investigation of the influence of inert solids on ignition sensitivity of organic powders
Institution:1. Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche (IRC-CNR), Piazzale Tecchio 80, 80125 Napoli, Italy;2. Dipartimento di Ingegneria Chimica Materiali Ambiente, Sapienza Università di Roma, Via Eudossiana, 18, 00184 Roma, Italy;3. Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università degli Studi Federico II, Piazzale Tecchio 80, 80125 Napoli, Italy;1. Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8656, Japan;2. State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui 230027, PR China;3. School of Chemical Machinery, Dalian University of Technology, Dalian, Liaoning 116024, PR China
Abstract:This work presents the results of the experimental characterization of the ignition sensitivity of solid inertant/combustible powders mixtures. Three inert solids (alumina, Kieselguhr, aerosil) and eleven organic powders have been considered and the following parameters have been determined: (1) the minimum ignition energy, (2) the minimum ignition temperature in cloud and (3) the minimum ignition temperature in 5 mm layer. The effects of the addition of inert solids are described and a simple model is proposed to represent the experimental results.Generally, increasing inert solid content in a powder leads to a higher minimum ignition energy as well as a higher minimum ignition temperatures in cloud and in layer. In some cases, the flammability is influenced above a threshold concentration value, which can be quite high (up to 85 wt.%). Indeed, the proposed model shows a zone below the minimum ignition concentration (MIC), which does not enable an efficient or safe inerting: either the admixed inert solid does not provide a sufficient effect, or it can even facilitate the ignition of the dust by notably improving its dispersability.The influence of key parameters such as the thermal conductivity or optical properties on the efficiency of the inerting by admixed solid need to be further assessed in a future work in view to better understand the mechanisms involved and to extend the scope to other types of oxidizable materials.
Keywords:Dust explosion  Ignition  Solid inertant  Organic powder  Experimental investigation
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