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Validation of discharge and atmospheric dispersion for unpressurised and pressurised carbon dioxide releases
Institution:1. Department of Chemical Engineering, UCL, London WC1E 7JE, United Kingdom;2. Dalian University of Technology, Dalian, People''s Republic of China;1. Department of Chemical Engineering, University College London, London WC1E 7JE, United Kingdom;2. INERIS, Dept. PHDS, Parc Technologique ALATA, BP 2, 60550 Verneuil-en-Hallate, France;1. School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK;2. School of Mathematics, University of Leeds, Leeds LS2 9JT, UK;1. Amirkabir University of Technology, Tehran, Iran;2. Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, Iran;1. Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT, UK;2. INERIS, Department PHDS, Parc Technologique ALATA, BP 2, 60550 Verneuil-en-Halatte, France;3. GexCon AS, PO Box 6015, Bergen Bedriftssenter, NO-5892 Bergen, Norway;4. School of Mathematics, University of Leeds, Leeds LS2 9JT, UK;5. Department of Chemical Engineering, University College London, London WC1E 7JE, UK;6. Health & Safety Laboratory, Harpur Hill, Buxton SK17 9JN, UK;7. National Center for Scientific Research “Demokritos”, Institute of Physical Chemistry, Molecular Thermodynamics and Modelling of Materials Laboratory, GR-153 10 Aghia Paraskevi Attikis, Greece;1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, China;2. Oil Field Reconnaissance Designing Institute of Jilin, PetroChina Jilin Oilfield Company, Songyuan, China
Abstract:This paper discusses the validation of discharge and subsequent atmospheric dispersion for both unpressurised and pressurised carbon dioxide releases using the consequence modelling package Phast.The paper first summarises the validation of the Phast dispersion model (UDM) for unpressurised releases. This includes heavy gas dispersion from either a ground-level line source (McQuaid wind-tunnel experiments) or an area source (Kit-Fox field experiments). For the McQuaid experiments minor modifications of the UDM were made to support line sources. For the Kit Fox experiments steady-state and 20-s finite-duration releases were simulated for both neutral and stable conditions. Most accurate predictions of the concentrations for finite duration releases were obtained using the UDM Finite Duration Correction method.Using experiments funded by BP and Shell and made available via DNV's CO2PIPETRANS JIP, the paper secondly summarises the validation of the Phast discharge and dispersion models for pressurised CO2 releases. This modelling accounted for the possible presence of the solid CO2 phase following expansion to atmospheric pressure. These experiments included both high-pressure steady-state and time-varying cold releases (liquid storage) and high-pressure time-varying supercritical hot releases. Both the flow rate and the concentrations were found to be predicted accurately.The above validation was carried out with no fitting whatsoever of the Phast extended discharge and dispersion models.
Keywords:Consequence modelling  Model validation  Discharge  Atmospheric dispersion  Thermodynamics
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